CENTRAL MATERIAL FOR CUSHION, AND CUSHION

专利摘要:
core material for cushion, and cushion. an object is to provide a hygienic pad that is of adequate thickness to provide repulsive force at or above a specified level and body holding property, is light in weight, has excellent air permeability, and is washable with water. the cushion core material 1 comprising the three-dimensional mesh-like structure, which is comprised of a thermoplastic polyethylene resin, a thermoplastic polyester elastomer or a mixture of a thermoplastic polyethylene resin and a thermoplastic polyethylene elastomer. the three-dimensional network-like structure has a first layer that includes a thermoplastic resin and a second layer that is stacked on a single surface or both surfaces of the first layer and includes a different thermoplastic resin from the thermoplastic resin of the first layer. The three-dimensional net-like structure has an impact elasticity of not lower than 13 cm, a hysteresis loss of not higher than 34% and not lower than 13%, and a thermal expansion index of 0 to 8% in the longitudinal direction before and after a hot air drying test which is carried out at a temperature of 90°c for 30 minutes with respect to polyethylene thermoplastic resin which is carried out at a temperature of 130°c for 30 minutes with regard to the thermoplastic polyester elastomer and which is carried out at a temperature of 90° C for 30 minutes with regard to the mixture of the thermoplastic polyethylene resin and the thermoplastic polyethylene elastomer.
公开号:BR112016019126B1
申请号:R112016019126-9
申请日:2015-02-23
公开日:2022-01-04
发明作者:Takaoka Nobuyuki
申请人:C-Eng Co., Ltd；
IPC主号:

专利说明:

Technical Field
[001] The present invention relates to a pillow core material that uses a three-dimensional net-like structure, as well as pillows produced by coating the core material with various medical care covers and pillows. Knowledge of Art
[002] A three-dimensional lattice-like structure formed by curved fused filaments of an extruded synthetic resin material from the random spiral-shaped multi-hole nozzle to be welded together and solidified is conventionally used as a core material for padding. .
[003] Cushion, e.g. mattress is required to satisfy various needs, such as recycling efficiency and low cost, in addition to various conditions to prove comfortable sleep, e.g. elasticity, adequate repulsive force, good maintenance property, vibration reduction property, stillness, air and light permeability. It is difficult, however, for the single three-dimensional lattice-like structure to satisfy all these physical properties. One mattress has been proposed to make one surface light and the other surface hard by stacking two-dimensional net-like assemblies having different densities of curvature (Patent Literature 1 and Patent Literature 2). Patent Literature 1, however, does not take into account luminosity and air permeability and does not teach concrete examples of the material. Patent Literature 2, on the other hand, changes the pitch of holes arranged in a longitudinal direction of a nozzle in each divisional area, as well as changing the density of ejected filaments and integrally molded into a multi-density lattice-like structure. The material used is, however, only polyester elastomer.
[004] A multi-layer net-like structure has been disclosed, in which a layer of thermoplastic elastic resin and a layer of non-thermoplastic elastic resin are stacked and fused to provide a stacked net-like body having substantially flattened surface and a Non-woven fabric made of continuous fiber is joined with a single surface of the stacked net-like body for the purpose of supporting and reinforcing (Patent Literature 3). This multi-layer net-like structure requires joining the non-woven fabric as the reinforcing layer to support the cushion material. This disclosure recommends using polyester for both the thermoplastic elastic resin layer and the non-thermoplastic elastic resin layer which are fused to or joined together in terms of recovery and recycling after waste and avoids the use of polyolefin.
[005] A layered cushion structure has been revealed, in which a cushion material made from a fiber assembly is placed on a surface layer and an interwoven fabric providing small cavities to release heat and moisture is stacked like a layer of fabric. back. The layered pad structure has at least two layers of pad material made of fiber assembly, and the hardness of the respective layers gradually decreases towards the surface layer (Patent Literature 4). This disclosure uses polyester elastomer ester for the pad material and avoids the use of polyolefins.
[006] A bed mattress has been proposed, in which a padding layer (hard cotton layer) formed from the double raschel knit is stacked on an upper surface of a pillow layer, and the entire surfaces are covered with a sheath (006) Patent Literature 5). Stacking the infill layer provides the function of increasing the degree of freedom following the strain pressure and moving the contact point supporting the compressive force even in response to a slight change. Cushion layer is a single layer and serves to receive a local external force transmitted from the padding layer relieves stress concentration (gains body pressure dispersion property) This configuration is unlikely to provide sufficient body holding function and eliminate the uncomfortable sinking feeling. The disclosure suggests using polyester as the material for both the cushion layers and the padding layer in terms of recycling efficiency, heat resistance and durability. This means that the core material is substantially made from 100% polyester.
[007] The techniques from Patent Literature 2 to Patent Literature 5 have the problem of a significant increase in total weight in order to ensure the repulsive force equivalent to polyolefin, reduce the uncomfortable sinking feeling due to excessive sinking and provide the function to hold the body.
[008] Various techniques have been proposed for a three-dimensional lattice-shaped structure formed by conventional extrusion molding to have filaments partially entangled in loops and a surface-two or surface-four method of molding the three-dimensional lattice-shaped structure. An example is described in Patent Literature 6 in order to mold a three-dimensional lattice-like structure. A proposed method of molding a three-dimensional net-like structure presses down fused filaments made of or primarily made of a thermoplastic synthetic resin from a block equipped with a nozzle having a plurality of holes in one edge, causing the free fused filament to fall between continuous conveyors that are entirely or partially submerged in water, and drag the filaments at a slower speed than the falling speed, so as to manufacture a three-dimensional lattice-like structure. Continuous conveyors are arranged to face each other to form a specific shape (eg quadrilateral) in a direction perpendicular to the extrusion direction. The gap between the continuous conveyors facing each other is set to be narrower than the width of an extruded filament assembly. Two surfaces of four surfaces from the outer periphery of the filament assembly are brought into contact with the conveyors downstream and upstream from the location where the conveyors are submerged in water.
[009] The prior art of the three-dimensional lattice-shaped structure has randomly formed loops and is shrunk by the application of heat. For example, in a mattress application, the cover is susceptible to wrinkling from repeated high temperature sterilization. This makes the user uncomfortable and can cause chafing from long-term use. Especially shrinkage of the three-dimensional net-like structure in the longitudinal direction has significant effect and high wrinkle probability.
[0010] Additionally, the prior art of the three-dimensional net-shaped structure is unlikely to perform the function according to the characteristics of the human body. For example, in a mattress application, the human body has the function of naturally adjusting compliance with posture control during sleep, extending and changing the position of the body, relaxing the muscles and body to equalize the body's load and readjust. body pressure. The proposed three-dimensional lattice structure, however, has insufficient structural characteristics following the natural fit function. There are a variety of needs for products using the three-dimensional net-shaped structure and needs for high quality products. This causes difficulty in satisfying both the diversity of needs to be adjusted to the characteristics of the human body and the needs for high quality products.
[0011] A cushion material made of urethane foam has excellent durability and body pressure dispersion property of a certain level and is conveniently employed for mattress. The pad material, however, has a problem of poor scraping force absorption performance, which is observed as a cause of chafing. Low-elastic urethane foam has been proposed as the material having excellent scraping force absorption performance. The low elasticity of urethane foam, however, has low air permeability, in addition to difficulty rolling and a temperature dependent change in hardness.
[0012] Using urethane having open cell foam for a mattress has been proposed (Patent Literature 7). Patent literature 7 describes that impregnating the urethane having the open cell foam with a resin having pressure sensitive adhesion provides excellent performance for capturing and collecting ticks. Urethane, however, originally has low repulsive strength, so even increasing thickness does not provide sufficient functions as a mattress.
[0013] A structured layer mattress formed from urethane foam has been proposed, in which a lower layer is made of high-density urethane foam, a middle layer is made of low-elastic urethane foam, and a top layer is made of filter foam having the open cell structure (Patent Literature 8 and Patent Literature 9). This mattress takes into account the repulsive property and the function of holding the body but uses the low air permeability urethane foam for the lower layer and the middle layer. This is likely to cause sweating during sleep and is undesirable in terms of hygiene. A proposed technique to solve this problem has air holes provided in a low elasticity mattress (Patent Literature 10). This technique is, however, insufficient to release heat and steam through the side face of the mattress and inlet air from the outside.
[0014] A three-dimensional lattice-like structure formed by bending a plurality of fused filaments into coil form to be thermally fused together has been proposed as an alternative to urethane foam having low water permeability and transpiration probability ( Patent Literature 5). Patent Literature 5 has proposed a double knitted raschel bonded with or stacked on a single surface or respective surfaces of the three-dimensional net-like structure. List of Patent Literature Citation
[0015] Patent Literature 1: JU S58-93270A Patent Literature 2 JP H07-189104A Patent Literature 3 JP H07-300757A Patent Literature 4 JP 2011-031456A Patent Literature 5 JP H08-336443A Patent Literature 6 JP 2001 -328153A Patent Literature 7 JP H11-169050A Patent Literature 8 JP 2004-173828A Patent Literature 9 JP 2004-180977A Patent Literature 10 JP 2005-312649A Invention Summary Technical Problem
[0016] An object of the invention is to provide a pad that provides repulsive force at or above a specified level, is light in weight, is easily handled and has sufficient heat resistance in terms of sanitization and sterilization.
[0017] Another object of the invention is to provide a configuration that is thermally expandable in a longitudinal direction and additionally has a hysteresis loss and an elastic property fit for the characteristics of the human body, thus satisfying a variety of quality needs.
[0018] Another object of the invention is to provide a hygienic pad that has a suitable thickness to provide repulsive force at or above a specified level and the property of holding the body, is light in weight, has excellent air permeability and is washable. with water. Solution of the problem
[0019] In view of the above problems, according to one aspect of the invention, there is provided a core material for cushion comprising a three-dimensional lattice-like structure in a plate-like shape that is formed by the spirally entangled of a plurality of filaments, which are made of or primarily made of a thermoplastic resin as a raw material, in random and partially bonded heat entanglements, wherein the three-dimensional lattice-like structure has a first layer that includes a thermoplastic resin and a second layer which is stacked on a single surface or both surfaces of the first layer and includes a thermoplastic resin different from the thermoplastic resin of the first layer, wherein the thermoplastic resin of the first layer has a higher melting temperature than the thermoplastic resin of the second layer layer, the first layer or the second layer forms the three-dimensional lattice-like structure that has a direction longitudinal direction corresponding to an extrusion direction, a lateral direction and a thick perpendicular direction to the extrusion direction and is comprised of a thermoplastic polyethylene resin, a thermoplastic polyester elastomer or a mixture of a thermoplastic polyethylene resin and a thermoplastic elastomer of polyethylene, wherein the three-dimensional net-like structure has an impact elasticity of not lower than 13 cm, a hysteresis loss of not higher than 34% and not lower than 13%, and an index thermal expansion from 0 to 8% in the longitudinal direction before and after a hot air drying test which is carried out at a temperature of 90°C for 30 minutes with regard to polyethylene thermoplastic resin, which is carried out at a temperature of 130°C for 30 minutes with regard to the thermoplastic polyethylene elastomer and which is carried out at a temperature of 90°C for 30 minutes with regard to the terrestrial resin mixture polyethylene moplastic and polyethylene thermoplastic elastomer. Forming the three-dimensional net-like structure to have stacked layers of different materials provides a low-cost bed mattress that has the function of holding the proper body, is light in weight and is easy to handle. In this configuration, the layer having relatively high heat resistance is placed on the outside. This configuration suppresses deterioration of the characteristics of the first layer even in the case where the three-dimensional net-like structure is heated to high temperature for the purpose of sterilization, heat retention and the like. The three-dimensional net-shaped structure of this aspect is an excellent three-dimensional net-shaped structure which has a low hysteresis loss, smoothness, and high repulsive characteristic, and provides an elastic property fit for the characteristics of the human body to meet a diversity of needs. for the elastic properties of the products and needs for the high quality of the products. This accordingly provides a three-dimensional net-like structure suitable for a pad material or a surface material used in health care products, bedding, furniture, vehicle metals and the like. For example, in a medical care mattress application, the proper elastic property of the three-dimensional net-like structure corresponds to the natural adjustment of human body functions during sleep to adequately suppress diaper rash and the like and assist the patient to sit properly. . The caregiver takes advantage of the repulsive force of the mattress to reposition the patient with less effort. Mattress hardness can be changed according to the mattress area. Additionally, the three-dimensional lattice-shaped structure has a characteristic of thermal expansion in the longitudinal direction. In an application for a mattress, this advantageously suppresses mattress shrinkage and cover roughness even in the case of high-temperature sterilization, as well as chafing due to roughness. The three-dimensional net-like structure of this aspect is readily heat-sterilized and readily dried it is thus unlikely to cause hospital-acquired infection. The provided three-dimensional net-like structure is suitable for producing a pad material required for medical treatment and care.
[0020] It is preferred that the first layer includes a polyolefin resin, and the second layer includes a polyester elastomer and/or polyurethane elastomer. In this configuration, the layer having relatively high heat resistance is placed on the outside. This configuration suppresses deterioration of the characteristics of the polyolefin resin layer even in the case where the three-dimensional net-like structure is heated to high temperature for the purpose of sterilization, heat retention and the like. Much filter, urethane, stiff cotton and the like can be used for the second layer, in place of the polyester elastomer and/or polyurethane elastomer. This is preferable to integrating the polyester elastomer with a pad.
[0021] The core material can be substantially comprised of the three-dimensional lattice-shaped structure. This simplifies the manufacturing process and eliminates the need for separately supplying a moisture-absorbing and fibrous moisture-releasing layer or a filler layer. This reduces component cost and manufacturing cost and additionally eliminates the need to remove the separate material joined with the three-dimensional net-like structure for recovery and recycling.
[0022] It is preferred that the layer including the polyolefin resin has a thickness of not less than 8 mm and less than 250 mm, and the layer including the polyester elastomer and/or polyurethane elastomer has a thickness of from 3 mm to 160 mm Controlling the thickness to this range maximizes the characteristics of the two materials, in other words, polyester or polyurethane and polyethylene, and reduces noise during rolling, changing body position, and the like.
[0023] According to another aspect of the invention, the core cushion material, at least a partial area on one side of the core cushion material facing the second layer, is covered with an air permeable cover. This takes advantage of excellent air permeability of the three-dimensional net-shaped structure placed inside.
[0024] In accordance with another aspect of the invention, in a medical pad comprising the core pad material, at least a partial area on one side of the core pad material facing the second layer is covered with a waterproofing material. Water. A patient who lies in bed for an extended period of time during long-term care at home or in the hospital experiences constriction of blood flow through capillaries due to site compression in the body and often has diaper rash caused by local necrosis of cells at the compressed site (mainly prominence of the body). Using the core material of the above aspect provides an effective mattress dispersion of body pressure to suppress local body compression and provides a suitable cushion as a posture holding device to hold and fix the whole body or part of a patient's body during operation in orthopedics and surgery. Covering the core material of the above aspect with a water impermeable sheet or cover allows for a hygienically required bed bath.
[0025] In view of the above problems, the invention provides a core material for pillow, comprising a three-dimensional net-like structure that is formed by spirally entangled filaments, which are made of or primarily made of a polyolefin resin, a polyester elastomer and /or polyurethane elastomer, or a blend of a polyethylene thermoplastic resin and a polyethylene thermoplastic elastomer with a raw material, in random and partially bonded heat tangles, and a lightweight urethane foam that is stacked on a single surface or both surfaces of the structure in the form of a three-dimensional network and have an open cell foam and/or a continuous space. Stacking lightweight urethane foam having open cell foam and/or continuous space protects the side of the body in case of side lying and provides comfortable, light sleep. This prevents deterioration of the characteristics of the lowest three-dimensional net-like structure even in combination with an electric blanket or a hot water bottle for the purpose of retaining heat and protecting from the cold in winter, improves heat resistance and evenly Warms the lying surface by the open cell structure. This also produces a cushion that suppresses sweat and provides coolness in summer, in combination with the excellent air permeability of the three-dimensional mesh structure.
[0026] The three-dimensional net-like structure can be configured to have a longitudinal direction corresponding to an extrusion direction, a lateral direction and a thickness direction perpendicular to the extrusion direction and is comprised of a polyethylene thermoplastic resin, a polyester thermoplastic elastomer or a blend of polyethylene thermoplastic resin and polyethylene thermoplastic elastomer. The three-dimensional net-like structure can be configured to have an impact elasticity of not lower than 13 cm and a hysteresis loss of not higher than 34% and not lower than 13%. The three-dimensional net-shaped structure can be configured to have a thermal expansion index of 0 to 8% in the longitudinal direction before and after a hot air drying test is carried out at a temperature of 90°C for 30 minutes under consideration. to the thermoplastic polyethylene resin, which is carried out at a temperature of 130° C for 30 minutes in consideration of the thermoplastic polyester elastomer and which is carried out at a temperature of 90° C for 30 minutes in consideration of the mixture of the thermoplastic polyethylene resin and the polyethylene thermoplastic elastomer.
[0027] The three-dimensional net-like structure preferably has a thermal expansion index of 0 to 8% in the lateral direction before and after the hot air drying test which is carried out at a temperature of 90°C for 30 minutes with consideration to the thermoplastic polyethylene resin, and which is carried out at a temperature of 130° C for 30 minutes with regard to the thermoplastic polyester elastomer.
[0028] It is preferable that the three-dimensional lattice-shaped structure has an anisotropic thermal expansion characteristic providing different thermal expansion rates in the longitudinal direction and in the lateral direction. The anxiotropic thermal expansion characteristic having different thermal expansion rates in the longitudinal direction and in the lateral direction enables the three-dimensional lattice-like structure to be adjusted for this application and the characteristics of the human body in the application.
[0029] It is preferable that the three-dimensional net-like structure has an impact elasticity change rate of not higher than 20% after repeated load testing.
[0030] It is preferable that the three-dimensional net-like structure has an apparent density of 0.025 g/cm3 to 0.2 g/cm3, a thickness of 5 mm to 500 mm in each layer and a filament diameter of 0.1 mm to 1.5 mm.
[0031] It is preferred that the thermoplastic polyethylene resin is selected from the group consisting of polyethylene, an olefin/αethylene copolymer resin which is primarily made of ethylene and an olefin containing 3 or more carbon atoms, and a copolymer resin of vinyl acetate/ethylene.
[0032] It is preferred that the blend of polyethylene thermoplastic resin and polyethylene thermoplastic elastomer is a blend of an α-olefin/ethylene copolymer resin, which is primarily made of ethylene and an α-olefin containing 3 or more carbon atoms. and the polyethylene thermoplastic elastomer, and a content of the polyethylene thermoplastic elastomer in the blend is not higher than 45% by weight.
[0033] It is preferred that the three-dimensional net-like structure has a plurality of surfaces, between which two surfaces, three surfaces or four surfaces are molded to have a profiled shape.
[0034] In one aspect the lightweight urethane foam has an impact elastic range of 25% to 85% measured in accordance with JIS K6400 as a form of lightweight urethane foam. The elastic impact in the above field provides, in combination with the lowest layer of the three-dimensional net-like structure, the repulsive force suitable for the lying surface.
[0035] In one aspect, the lightweight urethane foam has an open cell foam sized not lower than 5 cells by 25 mm and not higher than 40 cells/25 mm measured in accordance with JI K6400-1 . Appendix 1 as a form of lightweight urethane foam. The open-cell foam size in the above field satisfies both the warning effect evenly of the entire resting surface and the effect of light supply and comfortable sleep.
[0036] Lightweight urethane foam is a polyester urethane foam. Using polyester urethane foam is unlikely to cause water absorption and hydrolysis.
[0037] In accordance with a further aspect of the present invention there is a provided cushion comprising the core cushion material, wherein at least a partial area on one side of the core cushion material facing the lightweight urethane foam is covered with a cover. of permeable air. This takes advantage of excellent permeability of the core material to the cushion.
[0038] In accordance with a further aspect of the present invention there is a medically supplied cushion comprising the core cushion material, wherein at least a partial area on one side of the core cushion material facing the lightweight urethane foam is covered. with a water impermeable material. A patient who lies in bed for an extended period of time during long-term care at home or in the hospital experiences constrained blood flow through the capillaries due to local compression in the body and often has diaper rash from local necrosis of cells at the compressed site. (mainly bony prominence). Using the core material of the above aspect provides effective dispersion of body pressure on the mattress by suppressing local body compression and providing a suitable cushion as a posture-holding device for holding and securing a patient's entire body or body part. during operation in orthopedics and surgery. Covering the core material of the above aspect with a water impermeable sheet or cover allows for hot water sterilization and bed bath required in terms of sanitization. Advantageous Effects of the Invention
[0039] The above aspects of the invention provide a pad that provides repulsive force at or above a specified level, is light in weight, is easily handled, and has sufficient heat resistance in terms of sanitizing, sterilizing, and retaining heat in use. combined with an electric blanket or a hot water bottle. This provides significant potential in many industries. The above aspects of the invention have the characteristic of thermal expansion in the longitudinal direction and in the lateral direction, thus suppressing cushion shrinkage and cover roughness even in the case of high sterilization temperature, as well as chafing due to roughness. The above aspects of the invention have the characteristic of anxiotropic thermal expansion having different rates of thermal expansion in the longitudinal direction and in the lateral direction. This enables the three-dimensional net-like structure to be adjusted for this application and the characteristics of the human body in the application. Additionally, the above aspects of the invention have low hysteresis loss, light weight and high repulsion characteristic; and thus provides the elastic property suitable for the characteristics of the human body. This accordingly meets a diversity of needs for the elastic properties of the products and needs for the high quality of the products.
[0040] Additionally, aspects of the invention provide a hygienic pad that has a suitable thickness to provide repulsive force at or above a specified level and body grip property, is light in weight, has excellent air permeability, and is washable. with water. This provides significant potential in many industries. Brief Description of Drawings
[0041] Fig. 1 is a perspective view illustrating a cushion core material in accordance with a first embodiment of the invention; Fig. 2 A is a vertical sectional view illustrating the cushion core material according to the first embodiment of the invention. Fig. 2B is a vertical sectional view illustrating a cushion core material according to a second embodiment; Fig. 2C is a vertical sectional view illustrating a cushion core material according to a fourth embodiment. Fig. 2D is a vertical sectional view illustrating a cushion core material according to the fifth embodiment. Fig 2E is a vertical sectional view illustrating a cushion core material according to a sixth embodiment; Fig. 2F is a vertical sectional view illustrating a cushion core material according to the seventh embodiment; Fig. 2G is a vertical sectional view illustrating a core pad material according to an eighth embodiment; Fig. 3 A is a sectional view illustrating a cushion core material according to the ninth embodiment; Fig. 3B is a side view illustrating the cushion core material according to the ninth embodiment; Fig. 4A to 4G are sectional views illustrating respective layers of a core cushion material according to a third embodiment; Fig. 5 is a perspective view illustrating an apparatus for manufacturing pillow core material according to the first embodiment; Fig. 6 is a diagram illustrating the operations of the apparatus for manufacturing the pillow core material in accordance with the first embodiment; Figs. 7A and 7B are respectively a side view and a front view illustrating endless conveyors in the apparatus for manufacturing the cushion core material; Figs. 8A to 8F are side views illustrating apparatus for manufacturing core material for pads and endless conveyors of the modified configurations; Fig. 9A is a plan view illustrating endless conveyors in the apparatus for manufacturing the core pad material in the case of four molding surfaces. Fig. 9B is a side view illustrating the apparatus for manufacturing the cushion core material. Fig. 9C is a side view illustrating apparatus for manufacturing a core pad material of another configuration in the case of four molding surfaces. Fig. 9D is a plan view illustrating 4 molding surfaces by the apparatus for manufacturing the core pad material. Fig. 9E is a plan view illustrating three surfaces molded by the apparatus to manufacture the pillow core material; Fig. 10A is a plan view illustrating endless conveyors of a standalone unit configuration in an apparatus for manufacturing a core pad material in the case of four-surface molding; and Fig. 10B is a view illustrating endless conveyors in an apparatus for manufacturing a cushion core material having a slide plate provided at a flat end; Figs. 11 A to (h) are plan views and a front view illustrating various modifications from one nozzle to one; Figs. 12A and 12B are front views illustrating modifications of the endless conveyors in the apparatus to manufacture the core pad material in the case of four molding surfaces; Fig. 13A is a vertical sectional view illustrating a cushion core material according to the tenth embodiment; Fig. 13B is a vertical sectional view illustrating a cushion core material according to an eleventh embodiment; Fig. 13C is a vertical sectional view illustrating a cushion core material according to the twelfth embodiment; Fig. 13D is a vertical sectional view illustrating a cushion core material according to a thirteenth embodiment; Fig. 14A is a vertical sectional view illustrating a cushion core material according to the fourteenth embodiment; Fig. 14B is a vertical sectional view illustrating a cushion core material according to a fifteenth embodiment; Fig. 15 is a perspective view illustrating an apparatus for manufacturing a pillow core material according to the second embodiment; Fig. 16A is a vertical sectional view illustrating the periphery of an upper portion of a mouthpiece in a complex due to an apparatus for manufacturing the cushion core material of the second embodiment. Fig. 16B is a front view illustrating a lower portion of the complex mold; Figs. 17A and 17B are diagrams illustrating modifications of the apparatus to manufacture the cushion core material of the second embodiment; Figs. 18A, 18B and 18D are plan views illustrating various nozzle configurations in a mold; Fig. 18C is a front view of Fig. 18D; Figs. 19A through 19D are plan views illustrating various nozzle configurations in a mold; Fig. 20 is a diagram illustrating the operations of an apparatus for manufacturing a pillow core material in accordance with another embodiment; Figs. 21A and 21B are respectively a side view and a front view of the rollers in the apparatus for making the core pad material; Figs. 22A through 22G are side views illustrating apparatus for making core pad material and roll modifications; Fig 23 is a diagrammatic configuration illustrating part of an apparatus for manufacturing a cushion core material according to a fourth embodiment; Fig. 24 is a perspective view illustrating a cushion core material in accordance with a sixteenth embodiment of the invention; Fig. 25 is a II-II vertical sectional view illustrating the cushion core material of the sixteenth embodiment of the invention; Fig. 26 is a perspective view illustrating a cushion core material in accordance with a seventeenth embodiment of the invention; Fig. 27 is a perspective view illustrating a cushion core material in accordance with an eighteenth embodiment of the invention; Fig. 28 is a diagram illustrating a method of using the cushion core material of the eighteenth embodiment of the invention, and Fig. 29 is a diagram illustrating a method of forming a continuous fit. Description of Representations
[0042] The following describes embodiments of the present invention with reference to drawings Cushion core materials according to the first to ninth embodiments are described first. A cushion core material 1 according to the first representation is comprised of a three-dimensional net-like structure 41 in a plate-like form which is made of or primarily made of a thermoplastic resin as a raw material and is formed by spiral entanglement of a plurality of filaments in random and partially bonded to heat tangles as shown in Fig. 1 and Fig. 2 A. The three-dimensional net-like structure 41 is configured by stacking a layer 45 including a polyester elastomer and/or an elastomer polyurethane on a surface of a layer 43 including a polyolefin resin as the core or base.
[0043] The sectional structure of the filaments is solid in this representation but may be hollow. Hollow filaments are preferable since air is attached to the tubular bodies to provide air spring properties and special damping properties. This also suppresses curvature. Air inclusion also maintains the rigidity of the three-dimensional structure. The hollow configuration can be continuous or discrete. In one example, a filament may be configured to include both a hollow portion and a filled portion. The ratio of mixing the solid filaments to hollow the filaments is preferred hollow solid = 10 to 80 90 to 20. A preferable configuration uses hollow filaments in a middle portion and covers the outer periphery of the hollow filaments with solid filaments to provide the feeling of good touch.
[0044] The cross section of filaments is in a circular shape in the representation but may be in an atypical shape such as a triangular shape. Y shape or star shape.
[0045] A three-dimensional lattice-like structure used for respective layers (first layer and second layer) is formed by entangling a plurality of filaments randomly into loops and thermally welding the tangles. The three-dimensional net-like structure has a three-dimensional progression as a dense-sparse configuration having sparse portions of a lower bulk density and dense portions of a higher bulk density arranged alternately in an extrusion direction during fabrication.
[0046] The three-dimensional net-like structure can have any configuration, for example, a structure having harder edges, a structure including a surface layer and a back face layer having different thicknesses, a structure including a surface and a face back having different levels of lightness and an internally perforated structure.
[0047] The respective layers 43 and 45 of the cushion core material 1 of the invention preferably have hysteresis losses of not higher than 34%. The lowest hysteresis loss means the highest feedback force provided at the earliest time after a release. Hysteresis loss of less than 34% ensures high restoring strength and instead provides the lightness and high elasticity that the invention aims at. Hysteresis loss of higher than 34% undesirably leads to delay and low elastic repulsive force. The hysteresis loss is more preferably 15 to 34% and is further preferably 20% to 34%.
[0048] The bulk density of the respective layers 43 and 45 of the core material for cushion 1 is an important factor in providing lightness and high elasticity and is designated as appropriate. The apparent density is preferably 0.025 g/cm3 to 0.2 g/cm3 and is more preferably 0.04 g/cm3 to 0.09 g/cm3 . . Bulk density lower than 0.025 g/cm3 does not keep the shape, while bulk density higher than 0.20 g/cm3 is not suitable for mattress. .
[0049] Layers 43 and 45 of the invention are three-dimensional spring structures formed by the continuous looped filaments randomly welded in the molten state, which have a filament diameter (diameter) from 0.3 mm to 1.5 mm and are made of a thermoplastic resin or an elastomer. thermoplastic. The filaments can be irregular in shape or hollow in shape. Filament diameter is, however, an important factor in providing light touch. Excessively small filament diameter does not maintain the required hardness for damping properties, while excessively large filament diameter provides too much hardness. The diameter of the filament is so to be placed in a suitable field.
[0050] Layers 43 and 45 preferably have loop lengths of 5 to 50 mm or especially 8 to 15 mm. The loops on the surface can be laid out according to the purpose.
[0051] The thicknesses of the respective layers 43 and 45 are significantly related to lightness and high elasticity and are preferably 5 mm to 500 mm, more preferably 10 to 150 mm and furthermore preferably 30 to 110 mm. A thickness of less than 5 mm undesirably leads to low elasticity, while a thickness of greater than 500 mm undesirably leads to excessively high elasticity.
[0052] In the case of mattress, pillow or similar, the dimensions of layers 43 and 45 can be, for example, 300 to 2000 mm in width, 300 to 2500 mm in length and 2 to 120 mm in weight.
[0053] In the three-dimensional net-like structure of the invention, the thermal expansion index of the thermoplastic polyethylene resin in the longitudinal direction and in the lateral direction before and after a hot air drying test at 90°C is not more than 8% and is preferably not higher than 3%. The thermal expansion index of higher than 8% at 90°C undesirably causes difficulty in placing the three-dimensional lattice-like structure on the roof. The thermal expansion index of lower than 0% before and after the hot air drying test at 90°C undesirably causes the product to shrink during high temperature sterilization and cause the cover to wrinkle. In the three-dimensional net-like structure of the invention, the thermal expansion index of the polyester thermoplastic elastomer in the longitudinal direction and in the lateral direction before and after a hot air drying test at 130°C is no higher than 8% and it is preferably not higher than 3%. The thermal expansion index of higher than 8% at 130°C undesirably causes a difficulty in placing the three-dimensional grid-like structure on the roof. The thermal expansion index of lower than 0% before and after the hot air drying test at 130°C undesirably causes the product to shrink during high temperature sterilization and make the cover crinkle.
[0054] In the case where the three-dimensional net-like structure of the invention is used for pad material, the resin used, the filament diameter, loop diameter, surface layer, bulk density and shape should be properly selected according to the purpose of use and the position used. For example, in the case where a material suitable for the hardness preference in a country is selected and used for a layer, the bulk density should differ between a surface layer and an intermediate layer. The three-dimensional net-like structure can be molded with a mold to a configuration adapted for the purpose of use to such an extent that it does not damage the three-dimensional configuration and used for car seat, airplane seat, boat seat, chair and furniture. . In order to satisfy required performances, the three-dimensional net-like structure can be used in combination with a hard pad material, polyurethane or non-woven fabric. The material can be treated to have fire retardant, non-flammable, antibiotic property and color.
[0055] With regard to the material of this three-dimensional net-like structure, it is preferable to use a thermoplastic polyethylene resin for layer 43 and a thermoplastic polyester elastomer for layer 45. The stacking sequence can be reversed.
[0056] The thermoplastic polyethylene resin of layer 43 is preferably a low density polyethylene resin having a bulk density of not higher than 0.94 g/cm 3 and is more preferably an ethylene α-olefin/ethylene copolymer resin and one three or more carbon atoms containing α-olefin. Using material having the bulk density of higher than 0.94 g/cm3 undesirably provides the pad material hard. The bulk density is more preferably not higher than 0.935 g/cm3 and is further preferably not higher than 0.91 g/cm3 . The lower volume density limit is preferably no lower than 0.8 g/cm3 and is more preferably no lower than 0.85 g/cm3 in terms of strength maintenance.
[0057] The polyolefin resin included in layer 43 is preferably an α-olefin/ethylene copolymer and is more preferably a copolymer of ethylene and a three or more carbon atoms-containing α-olefin described in JPH06-293813 A. Examples of the three or more α-olefin containing carbon atoms includes propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1 -undecene, 1-dodecene, 1-tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-nonadecene and 1-eicosene. Preferably they are 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene, 1-tridecene, 1- tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-nonadecene and 1-eicosene. Two or more of these α-olefins may be used. The α-olefin content in the copolymer is generally 1 to 40% by weight.
[0058] This copolymer can be obtained by copolymerizing ethylene with an α-olefin using a catalyst system including a specific metallocene compound and an organometallic compound as the configuration base.
[0059] The polyester elastomer and/or polyurethane elastomer included in layer 45 is preferably a thermoplastic polyester elastomer and is more preferably a thermoplastic polyester elastomer block copolymer (A) including a high melting point crystalline polymer segment (A) primarily made of a crystalline aromatic thermoplastic polyester elastomer unit and low melting point polymer segment (b) primarily made of an aliphatic polyether unit and/or an aliphatic thermoplastic polyester elastomer unit as main components.
[0060] Among thermoplastic elastomers, a polyester block copolymer (polyester elastomer) including a crystalline aromatic polyester unit as the hard segment and an aliphatic polyether unit such as poly(alkylene oxide) glycol and/or a polyester unit aliphatic such as polylactide with the light segment has excellent low-temperature and high-temperature properties and has relatively low temperature dependence stiffness.
[0061] The bulk density of the three-dimensional net-like structure using the thermoplastic polyester elastomer as raw material is preferably 1.01 to 1.60g/cm3 and is more preferably 1.05 to 1.20 g/cm3 .
[0062] Polyester thermoplastic elastomer is preferably used in terms of decreased temperature dependence over a wide temperature field. Polyester thermoplastic elastomer includes a high melting point crystalline polymer segment (a1) made from a crystalline aromatic polyester unit and melting point polymer segment (a2) made from an aliphatic polyether unit and/or an aliphatic polyester unit such as main components. The high melting point crystalline polymer segment (a1) is a polyester primarily made of an aromatic dicarboxylic acid or this ester-forming derivative and a diol or this ester-forming derivative. Concrete examples of aromatic dicarboxylic acid include terephthalic acid, isophthalic acid, phallic acid, naphthalene-2,6-dicarboxylic acid, naphthalene-2,7-dicarboxylic acid, anthracine dicarboxylic acid, diphenyl-4,4'-dicarboxylic acid, diphenoxyethane dicarboxylic acid , diphenyl ether dicarboxylic acid, 5-sulfoisophthalic acid and sodium sulfoisophthalate-3. Aromatic dicarboxylic acid is mainly used, but part of the aromatic dicarboxylic acid is mainly used, but part of the aromatic dicarboxylic acid can be substituted as appropriate with an alicyclic dicarboxylic acid and such as 1,4-cyclohexane dicarboxylic acid, cyclopentane dicarboxylic acid or 4,4'-dicyclohexyldicarboxylic or with an aliphatic dicarboxylic acid such as adipic acid, succinic acid, oxalic acid, sebacic acid, dodecanedioic acid or dimer acid. Ester-forming derivatives of these dicarboxylic acids, for example lower alkyl esters, aryl esters, carbonates and acid halides can be used similarly. Concrete examples of the diol are diols having a molecular weight of not more than 400. For example, preferred are aromatic diols such as xylylene glycol, bis(p-hydroxy)diphenyl, bis(p-hydroxy)diphenylpropane, 2,2'- bis[4-(2-hydroxyethoxy)phenyl]propane, bis[4-(2-hydroxyethoxy)phenyl]sulfone, 1,1-bis[4-(2-hydroxyethoxy)phenyl]cyclohexane, 4,4'- dihydroxy-p-terphenyl and 4,4'-dihydroxy-p-quartphenyl. Ester-forming derivatives of these diols, for example acetyls and alkali metal salts can be used similarly. Two or more of these dicarboxylic acids and derivatives thereof or two or more of these diols and derivatives thereof may be used in combination. A preferred example of the high melting crystalline polymer segment (a1) is a poly(butylene terephthalate) unit derived from terephalic acid and/or dimethyl terephthalate and 1,4-butanediol. A poly(butylene terephthalate) and terephthalic acid derivative and/or dimethyl terephalator and a poly(butylene isophthalate) unit derived from isophalic acid and/or dimethyl isophalate and 1,4-butanediol are also preferably used.
[0063] The low melting polymer segment (a2) of the polyester thermoplastic elastomer used in the invention is an aliphatic polyether and/or an aliphatic polyester. Examples of the aliphatic polyether include poly(ethylene oxide) glycol, poly(propylene oxide) glycol, poly(tetramethylene oxide) glycol, poly(hexamethylene oxide) glycol, copolymers of ethylene oxide and propylene oxide, ethylene oxide addition of poly/propylene oxide polymer) glycol and glycol copolymer of ethylene oxide and tetrahydrofuran. Examples of aliphatic polyesters include poly(e-caprolactone), polyenantholactone, polycaprylolactone, polybutylene adipate and polyethylene adipate. Among these adipate polyethers and/or adipate polyesters, in terms of the elastic property of the resulting polyester block copolymer, preferably used are poly/tetramethylene oxide) glycol, ethylene oxide addition product of poly(propylene oxide) glycol, oxide glycol copolymer of ethylene and tetrahydrofuran, poly (e-caprolactone) polybutylene adipate and polyethylene adipate. Among them, especially preferably used are poly(tetramethylene oxide) glycol, ethylene oxide add poly(propylene oxide) glycol product and glycol copolymer of ethylene oxide and tetrahydrofuran. The number average molecular weight of the low melting polymer segment is preferably approximately 300 to 6000 in copolymerized form. The amount of copolymerization of the low melting point polymer segment (a2) in the polyester thermoplastic elastomer used in the invention is not specifically limited but is preferably 10 to 90% by weight, more preferably 30 to 85% by weight and further preferably 50 to 80 % by weight. The amount of copolymerization of the low melting point polymer segment (a2) of less than 10% by weight provides the poor flexibility and poor resistance to bending fatigue. Low melting point polymer segment copolymerization amount (a2) of higher than 90% by weight, on the other hand, provides insufficient mechanical properties, insufficient high temperature properties, insufficient oil resistance and insufficient chemical resistance.
[0064] The thermoplastic polyester elastomer used in the invention can be produced by any known method. Available methods include a method of polycondensation of a product reaction by the transesterification of a lower alcohol diester of the dicarboxylic acid, an excess of the low molecular weight glycol and a low melting point polymer segment component in the presence of a catalyst and a method of polycondensation of the reaction of a product by the esterification of a dicarboxylic acid, an excess of glycol and a segment component of the low melting point polymer in the presence of a catalyst.
[0065] Any of the above block copolymers can be used alone or a mixture of two or more of the above block copolymers can be used.
[0066] Additionally, a blend including a non-elastomer component or a copolymer including a non-elastomer component can also be used in the invention.
[0067] The polyurethane elastomer is not specifically limited but can be any elastic polymer having urethane bond in the backbone. The polyurethane elastomer can be, for example, a block copolymer including a hard segment comprised of a diisocyanate and a glycol and a light segment comprised of a polyester, a polyether, a polycarbonate or an aliphatic polyol with a diisocyanate as appropriate. One or a mixture of two or more polyurethane elastomers can be used An antimicrobial, non-combustible or flame retardant material can be used with the polyurethane elastomer as the raw material to provide a layer including the polyurethane elastomer with the corresponding function.
[0068] The melting point of the low density propylene in layer 43 is preferably 100°C to 135°C. The melting point of the thermoplastic elastomer is preferably 155°C or higher to maintain the best durability and is most preferably 160°C. °C or higher to improve the best durability. An antioxidant, lightfastening agent or the like may be added as appropriate to improve durability. Increasing the molecular weight of the thermoplastic resin is also effective in improving heat durability and permanent placed strength.
[0069] The following describes a method of measuring and an apparatus for measuring the rate of decrease in filament diameter of polyethylene resin. Capilograph 1D (manufactured by Toyo Seiki Seisaku - Sho, Ltd.) is used for filament diameter decrease index measurement apparatus. The raw material resin is extruded at an extrusion rate of 3g/10 min by applying downward pressure to a capillary having an inner diameter D1 of 1.0 mm Φ and a length of 10 mm at a temperature of 190°C. The resin filaments of the extruded raw material are cooled by an alcohol. D2 represents a diameter of the filament cut in a cross section. The filament diameter decrease index is calculated as D2/D1. The filament diameter decrease index is measured at each raw material resin shear index.
[0070] A measurement method and an apparatus for measuring the rate of decrease in the diameter of the polyester thermoplastic elastomer filament are similar to those described above, except that the temperature is changed to 210°C.
[0071] The melt flow index (hereinafter referred to as MFR) of the polyethylene resin is 3.0 at 35 g/10 min.
[0072] The filament diameter decrease index of the polyethylene resin is preferably 0.93 to 1.16 at 24.3 sec-1 shear index, 1.00 to 1.20 at 60.8 sec-1 shear index, 1.06 to 1.23 at 121.6 sec-1 shear rate, 1.11 to 1.30 at 243.2 sec-1 shear rate, 1.15 to 1.34 at 608.0 sec-1 shear rate and 1.16 to 1.38 at 1216 sec-1 shear rate.
[0073] The melt flow index (hereinafter referred to as MFR) of polyester thermoplastic elastomer is 3.0 at 35 g/10 min.
[0074] The filament diameter decrease index of the thermoplastic elastomer polyester is preferably 1.10 to 1.38 at 60.8 sec-1 shear index, 1.12 to 1.39 at 121.6 sec-1 shear index, 1.15 to 1.42 at shear index from 243.2 sec-1, 1.17 to 1.43 at the shear index of 608.0 sec-1 and 1.19 to 1.47 at the shear index of 1216 sec-1.
[0075] The continuous filaments of the thermoplastic resin used to form the three-dimensional net-like structure of the invention can be combined with another thermoplastic resin to form a composite in such a range that it does not adversely affect the object of the invention. The composite form may be composed of filaments.
[0076] The composite three-dimensional net-like structure can be, for example, an elastomer layer/non-elastomer layer/elastomer layer sandwich structure, one of the layered structures of elastomer layer/non-elastomer layer and a composite structure in which a non-elastomer layer is placed partially in a central part in an elastomer layer of a matrix.
[0077] The three-dimensional net-shaped structure of the invention can be any suitably selected and multi-layer three-dimensional net-shaped structure to satisfy the performances required between various three-dimensional net-shaped structures, for example those having different loop sizes, those having different filament diameters, those having different compositions and those having different densities. Cushion binding or non-binding is designated according to the application and the relationship to the cover. In composite or multilayer structure using elastomer, the melting point makes it closer to the melting point of non-elastomer resin. A plurality of extrusion machines can be used to produce the composite or multi-layer structure.
[0078] Additionally, the three-dimensional net-like structure can be connected and integrated with a case or a padding layer to provide a seat cushion. A hard pad (preferably made of thermally bonded elastomer based fibers) is used as a padding layer and is thermally bonded and integrated with a case to provide a pad.
[0079] A cushion core material 2 according to a second embodiment (shown in Fig. 2 A) differs from the cushion core material 1 according to the first embodiment in that a layer 45 including a thermoplastic polyethylene resin and a thermoplastic elastomer of polyethylene is stacked instead of layer 45 including the polyester elastomer and/or the polyurethane elastomer.
[0080] Cushion core material 2 according to the second representation (shown in Fig. 2B) differs from cushion core material 1 according to the first representation so layer 45 including polyester elastomer and/or elastomer Polyurethane is stacked on both surfaces of layer 43 including the polyolefin resin as the center or base. Each layer is formed by four molding surfaces to have flat surfaces. In the core material for pad 1 according to the first embodiment, predetermined inner-depth areas of the side faces are formed to have the highest density, and a central inner area is formed to have the lowest density. In other words, predetermined interior depth areas of all surfaces except the top face and bottom face are formed to have the highest density.
[0081] A core material for cushion 3 according to a third embodiment is configured such that each layer or at least one layer has a surface of an atypical shape or polygonal shape. Examples of this configuration include a core material 3A having a convex surface (shown in Fig. 4A), a core material 3B having a concave surface (shown in Fig. 4B), a core material 3C having continuously formed concave-convex surface ( shown in Fig. 4C), a core material 3D having a clamped surface (shown in Fig. 4D), a core material 3E having a corrugated surface (shown in Fig. 4E), a core material 3F having curved edges (shown in Fig. Fig. 4F), a core material 3G having predetermined angled beveled edges (45 degrees in the illustrated example) (shown in Fig. 4G) and suitable combinations thereof. A concave/convex surface can be provided only on a surface lying in a layer having the surface lying. A concave/convex surface can be formed on each layer, and the respective layers can be stacked such that the concave/convex surfaces are opposite each other. In the latter case, the respective layers may be stacked such that a convex surface of one layer is fitted to a concave surface of the other layer, or may be stacked such that convex surfaces come into contact with each other.
[0082] A core material for pad 4 according to a fourth representation (shown in Fig. 2C) or configured to have a single or a plurality of (two in the illustrated example) cavities 4A and 4B formed in a layer, in order to achieve further cost reduction. A cushion core material 5 according to a fifth embodiment (shown in Fig. 2D) is configured to have recycled members 5C and 5D of identical material or different materials, for example recycled veneer boards or recycled cut-off boards, placed in cavities 5A and 5B which are formed in a layer similarly to cavities 4A and 4B in the central pad material 4 of the fourth embodiment. Recycled board members are placed for the purpose of improving sound absorption energy and damping properties. A pad core material 6 according to a sixth embodiment (shown in Fig. 2E) is configured to have an angle or a plurality of (three in the illustrated example) beam as high density areas 6A, 6B and 6C formed at intervals. predetermined by partially increasing the density in the inner thickness direction of each layer of core material for pad 1 of the first representation. This configuration improves sound absorbing energy, damping properties and impact resistance. A cushion core material 7 according to the seventh embodiment (shown in Fig. 2F) is configured to have a single or a plurality of (one in the illustrated example) high density area 7A formed by partially increasing density in the direction of width inside the lowest layer (first layer) of the core material for pad 1 of the first representation. The configuration improves sound absorbing energy, damping properties and impact resistance. A core pad material 8 according to the eighth embodiment (shown in Fig. 2G) is configured to have a corrugated high density area 8A in the high density area location of the seventh embodiment. This configuration improves sound absorption energy, damping properties and impact resistance.
[0083] A core material for pad 9 according to the ninth embodiment (shown in Fig. 3A) is configured by stacking the respective layers through a sheet 9A (pore-free area). This configuration improves sound absorption energy, damping properties and impact resistance. The filaments (resin filaments) are entangled around sheet 9A. Sheet 9A can be supplied under full width as illustrated or may be supplied partially, for example in a central part In the central material for cushion 9 of the ninth representation (shown in Fig. 3B), sheet 9A is formed into a corrugated shape approximately for the purpose of improving sound absorbing energy, damping properties and impact resistance. The corrugated shape is formed by the lower drag speed of the roller than the falling speed of the resin filaments as described later. The range, height and width of each waveform on sheet 9A is dependent on manufacturing conditions and is not limited to the illustrated example. In the case of the narrow waveform gap on sheet 9A, adjacent waveforms can be joined together. A slit (linear across the socket) 75a shown in Fig. 11 E may be employed for the ninth representation.
[0084] (Apparatus for Fabricating Cushion Core Material) The following describes an apparatus 10 for manufacturing cushion core materials of the first to ninth embodiments. As shown in Fig. 5, this manufacturing apparatus 10 includes extrusion molding machine 11, a pair of endless conveyors 14 and 15 configured to have endless belts 12 and 13 (shown in Fig. 7), an ignition motor 16 configured to drive the endless belts 12 and 13, a transmission 17 configured to have chains and gears and change the motion speeds of the endless belts 12 and 13, a water tank 18 configured to make the pair of endless conveyors 14 and 15 partially submerged in water, a controller 19 and various gauges and indicators.
[0085] Endless belts 12 and 13 are configured to couple a plurality of metal (e.g. stainless steel) plate members 20 crossing predetermined gaps 22 (shown in Fig. 8A) with a plurality of (e.g. , two) endless chains 12a and 13a (shown in Figs. 7A and 7B) by means of screws (not shown). A belt 23 of, for example, slack-free stainless steel mesh (wire) 22 as shown in Fig. 8B may alternatively be used. This mesh belt is formed by combining spirals and rods (striations). Various mesh belts can be formed by changing the shapes, the thread diameters and the releases of these two elements. The mesh belt is smoothly movable, easily keep the belt surface in a horizontal position, and has high resistance to high temperature and easy repair and maintenance. As shown by the dotted lines in Fig. 7, the stainless steel mesh belts 23 can be provided around the outer peripheries of the endless belts 12 and 13. This is advantageous to prevent irregularities from forming at the gaps 22. plate 20 is formed into a rectangular sectional shape but can be formed into various other sectional shapes, for example, a convex shape 24 (shown in Fig. 8C), a concave shape 25 (shown in Fig. 8D), a clamped shape 26 (shown in Fig.8E or a continuous concave-convex shape 27 (shown in Fig.8F).
[0086] As shown in Fig. 7, the endless conveyor 14 has a vertically placed drive shaft 14b having a sprocket 14A on which the endless chain 12a is wound, on a vertically placed drive shaft 14d having a sprocket 14c. The endless conveyor 15 is driven in sync with the endless conveyor 14. The endless conveyor 15 has a vertically placed drive shaft 15b having a sprocket 15A on which the endless chain 13a is wound, and a drive shaft vertically placed 15d having a sprocket 15c.
[0087] As shown in Fig. 6, the water tank 18 is configured to make a predetermined part of the apparatus 10 for manufacturing the cushion core material submerged in water and thereby cooling and solidifying a filament assembly 21 in the molten state. . A water level H is preferably placed at or above the height of the lower ends of the inclined planes 37a and 37b of the chutes 36 (shown in Fig. 6). The water level H is placed independently of the height at which the gutters 36 are placed but is placed based on the lower ends of the inclined planes 37a and 37b. Part of the endless carrying belts 14 and 15 can be exposed above water. The water level H is preferably set to satisfy 0_<Wd_< 45 (mm), where Wd denotes the height of the lower ends of sloping surfaces 37a and 37b, is more preferably set to satisfy 0_<Wd_<30 (mm) and is further preferably set to satisfy 0_<Wd_<22 (mm). The water level H is preferably equal to or higher than the height of the lower ends of the troughs 36.
[0088] As shown in Fig. 5, the extrusion molding machine 11 includes a container 31, a material feed port 32 that is provided in the upper portion of the container 31, a mold 33, and a nozzle 34 that is detachable. mountable to a lower end of the mold 33. The range of the internal mold temperature of the extrusion molding machine 11 can be set from 100 to 400°C, and the extrusion index can be set from 20 to 200 kg/hour. The pressure of 33 ranges from 0.2 to 25 MPa and can be based on, for example, the ejection pressure of a 75 mm screw. In the case where the thickness of each layer in the three-dimensional net-like structure exceeds 100 mm, equalization of the mold pressure by a gear pump or the like may be required. In this case the internal pressure of the mold should be increased by the gear pump or the like to evenly eject the filaments from the entire mold area. The respective forces of endless conveyors 14 and 15 are freely movable to form the shape of a three-dimensional web-like sheet. A product having a desired density and a desired strength is manufactured by adjusting the shape of the nozzle 34 of the mold 33 (density or diameter of the holes H) and adjusting the conveying speed of the endless conveyors 14 and 15. This meets a variety of needs. for the products.
[0089] As shown in Fig.6, filaments 20 made of a thermoplastic synthetic resin are entangled in loops at random and are thermally bonded to each other at contacting portions. Fabrication apparatus 10 includes chutes 36 which are placed below nozzle 34, water supply tubes 38 which are placed above chutes 36 and has water supply ports 39 at the ends of the water supply assembly. The rails 36 are located below the nozzle 34 and include a pair of longer side rails placed to face each other crossing longer side faces of the failing filament assembly 21 and (optionally) a pair of shorter side rails placed to face a the other crossing shorter side faces of the filament assembly 21 and forms an open molding at the lower end. The front rails 36 respectively have sloping planes 37a and 37b which are sloping downwards towards the filament assembly 21. Similarly the shorter front side rails respectively have sloping planes which are sloping downwards towards the filament assembly 21.
[0090] Water supply ports 39 are provided on supply pipes 38 arranged under approximately the entire length in the longitudinal direction above the troughs 36 to supply cooling water to the inclined planes 37a and 37b. Supply pipes 38 are connected to a countercurrent supply of water supply (not shown). Water cooling can be provided for shorter side chutes by adjusting the water flows from the supply pipes 38 or by providing similar supply pipes (not shown) above the shorter side chutes.
[0091] The following describes an apparatus 50 for manufacturing a cushion core material such as a two to four surface molding machine shown in Figs. 9A and 9B. Apparatus 50 for manufacturing the core material for pad includes endless conveyors 54 and 55 which correspond to endless conveyors 14 and 15 of two molding surfaces shown in Fig. 7 and respectively have rotating shafts 54a and 55a, and a pair of rollers. 56 and 57 which are placed at respective ends in the longitudinal direction of the endless conveyors 54 and 55 to have rotational axes perpendicular to the endless conveyors 54 and 55 and are configured to be rotatable about the rotation of the axes 56a and 57a. Spindle 54a has bevel gears 54b and 54c. Rotary shafts 56a and 57a respectively have bevel gears 56b and 57b. Bevel gears 54b and 54c mesh with bevel gears 56b and 57b. The rotary axes 54a and 55a are synchronously driven via a current C by means of a motor M, so that the rotary axes 56a and 57a are driven synchronously. The other ends of the rotary shafts 56a and 57a are supported by bearings 58a and 58b. As shown in Fig. 9C, a pair of short endless conveyors 59a and 59b having similar configuration to that of endless conveyors 54 and 55 can be arranged perpendicularly. This configuration ensures the most accurate molding and improves dimensional accuracy. This apparatus can be applied to four molding surfaces as shown in Fig.9D or applied to three molding surfaces as shown in Fig.9E. Two molds can be provided according to the type of structure in the form of a three-dimensional net for extruding filaments in parallel. This doubles production efficiency.
[0092] As shown in Fig. 10A, a modified configuration in place of the synchronous driving system described above provides separate driving sources (e.g., motors) to independently drive endless conveyors 64 and 65 and rollers 66 and 67 (or conveyors). without end). This modified three-surface or four-surface molding configuration includes the endless conveyors 64 and 65 having rotating shafts 64a and 65a, and the pair of rollers 66 and 67 which are placed at respective ends in the longitudinal direction of the endless conveyors 64 and 65 to have rotational axes perpendicular to the endless conveyors 64 and 65 and are configured to be rotatable about the rotation of the axes 66a and 67a. Separate motors M are provided for rotary axes 66a and 67a to independently drive rotary axes 66a and 67a. The other ends of the rotary shafts 66a and 67a are supported by bearings 68a and 68b. As shown in Fig. 10B, another modified configuration omits the pair of rollers 66 and 67, rotating shafts 66a and 67a, bearings 68a and 68b and M motors from the above configuration and provides slide rails 69a and 69b which have polytetrafluoroethylene containing surfaces and are placed at the positions of rollers 66 and 67. This simplifies the driving mechanism. These gutters 69a and 69b are configured in an arc shape in the side view to gradually narrow the bottom gap and are formed in a rectangular shape in the plan view.
[0093] Nozzle holes 34 are formed face down to make the filaments fall out. The holes can be arranged at equal intervals or at different intervals. The plurality of holes can be arranged in any of several orders, for example zigzag or at right angles. An available method of changing the order density intentionally increases the density only in the end areas. A variety of product needs are satisfied by changing the nozzle configuration. Available examples of the nozzle include a nozzle 71 which has approximately 3500 H holes of 0.5 mm in diameter arranged at substantially equal intervals in an area of 1.0 m to 180 mm (the size of the area filled with the holes of the H nozzle occupies 90% of the total area nozzle 71) (shown in Fig. 11A); a nozzle 72 having a higher density of holes H in a peripheral area 72a (shown in Fig. 11B); a mouthpiece 73 having a higher density of holes in a portion of the frame 73a to form grid-like areas (shown in Fig. 11C); a mouthpiece 74 having slits (linear through holes) 74a to 74c formed parallel to each other in a shorter direction, in addition to a large number of holes H (shown in Fig. 11D); a mouthpiece 75 having a slit (linear through the hole) 75a formed in a central part in the longitudinal direction, in addition to a large number of holes H (shown in Fig. 11E); a mouthpiece 76 having a slit (linear through hole) 76a formed in the longitudinal direction at a position close to a longitudinal side, in addition to a large number of holes H (shown in Fig. 11F ); and a mouthpiece 77 that includes areas 77c and 77d without H-holes formed at predetermined locations for cavity formation and has rectangular guide members (e.g., pipes) 77a and 77b that extend below areas 77c and 77d (shown in Figures 11G and 11H). The density of holes H formed in the nozzle is preferably 1 to 5 holes/cm 2 .
[0094] (Cushion Core Material Fabrication Method) The following describes an exemplary method of manufacturing the cushion core material 1 of the representation, but this method is not restrictive. As described in, for example, JP 2001-328153A, a raw material including polyethylene or a thermoplastic elastomer as the main component is melted at a melting temperature that is higher than the melting point of the main component by 10°C at 20°C. Melt raw material is fed into mold 33. Upon application of pressure, a plurality of filaments are ejected from a plurality of extrusion holes of nozzle 34 at a lower end to form a filament assembly. 21 according to the order of the plurality of extrusion and free-fall holes. In the case where the polyolefin resin and the polyester elastomer and/or polyurethane elastomer have significantly different melting temperatures or have significantly different property changes in the cooling process, a general manufacturing process individually produces the respective layers in different cooling tanks. water 18 or in separate processes and stacks the respective layers to produce the core material for pillows 1. The respective layers are produced by the following procedure. A thermoplastic resin as the raw material of each layer is heated and dried for the purpose of preventing hydrolysis or the like and is supplied from the material feed port 32 into the container 31. A final agent, an antimicrobial, a flame retardant and other additives may be added as appropriate. In describing this here, the melting temperature is obtained by differential scanning calorimetry.
[0095] The range of the internal temperature of the mold can be set from 100 to 400°C, and the extrusion index can be set from 20 to 200 Kg/hour. The internal pressure of the mold 33 can be based on, for example, the ejection pressure of a 75 mm screw and reaches approximately 0.2 to 25 MPa.
[0096] The diameter of the nozzle hole in the mold corresponds to the diameter of the filament of the filaments of the three-dimensional net-like structure and is preferably 0.2 to 4.0 mm and more preferably 0.4 to 1.8 mm.
[0097] The filaments in the molten state are received by at least the pair of right and left gutters 36 (WO 2012/157289A ) to which water or heated water is supplied and comes into contact with one another to be fused, forms a structure in three-dimensional net shape and reaches the water surface. The properties of the three-dimensional net-like structure are determined according to the angle of the troughs 36, the flow of water supplied, the diameter of the extrusion holes, the distances between the nozzle surface, troughs and drag-off conveyors, the viscosity resin melting point, the diameter and ejection rate of the extrusion holes, the loop diameter and the filament diameter of the filaments. The filament diameter (diameter) is 0.1 to 1.8 mm, and the level of the diameter (length) of random loops is 5 mm to 50 mm.
[0098] The filaments of the filament assembly located on the peripheral longitudinal side faces contact the inclined planes 37a and 37b of the troughs 36 in which the water flows. This configuration disturbs the falling trajectory vertically, and the filaments are entangled with adjacent filaments in the loops and are slid down the inclined planes 37a and 37b with the flow of water or heated water supplied from the supply pipes 38. The filaments directly receive the effect of gravity and are entangled together along the inclined planes 37a and 37b to form loops.
[0099] Water supply ports 39 are provided on supply pipes 38 which are arranged in the longitudinal direction above respective troughs 36 to supply water or heated water at a temperature ranging from 10 to 90°C or preferably 40 to 60°C. °C for the respective inclined planes 37a and 37b. Supply pipes 38 are connected with a counterflow water supply source. Heated water can be supplied to the troughs 36 by adjusting the water flows of the supply pipes 38.
[00100] The filaments of the filament assembly that do not also come into contact with the inclined planes of the troughs but fall through the molding opening. The filaments passing through the proximity of the lower sides of the slants 37a and 37b between the filaments passing through the mold opening contact the filaments slid down the slants 37a and 37b to be entangled in loops. The filaments fall, while the disturbance of the falling trajectory by the entangled contact is propagated to adjacent filaments in the central direction within a certain range. The filaments passing through the center of the opening of the open mold reach the surface of the water. The drag speed of the endless conveyors 14 and 15 is lower than the falling speed of the filament assembly. The respective filaments reaching the surface of the water are curved and are entangled in loops in the vicinity of the surface of the water. The speed of endless conveyors 14 and 15 is preferably 5 to 40 m/hour. The water level H of the water tank 18 is preferably equal to or higher than the height of the lower ends of the sloping planes 37a and 37b of the gutters 36. The water level H is set irrespective of the height at which the gutters 36 are placed but is placed based on the lower ends of the inclined planes 37a and 37b. Part of endless conveyor belts 14 and 15 may be exposed above water.
[00101] The assembly of the free-falling filaments between the pair of partially submerged endless conveyors 14 and 15 is drag speed lower than the falling speed. The gap between the pair of endless conveyors 14 and 15 is set to be narrower than the width of the molten resin extruded assembly. Both surfaces or a single assembly surface of the molten resin is brought in contact with the auger conveyors 14 and 15 in the downstream or downstream direction from the position where the auger conveyors 14 and 15 are submerged in water. The respective surface portions of the molten thermoplastic resin assembly fall into endless conveyors 14 and 15 and move into the molten thermoplastic resin assembly to densify. The respective surface portions accordingly have a lower porosity than the central portion which directly falls into the water and have a wider number of intersections compared to the central portion having the higher porosity. This significantly increases tensile strength. The surface portions having the lowest porosity have the smallest pore area and serve as impact absorbing layers.
[00102] The filament assembly 21 is dragged and fed by the endless conveyors 14 and 15. The filament assembly 21 in fixed form is placed between the rollers and withdrawn from the water tank 18.
[00103] A procedure of forming a three-dimensional net-shaped structure into an atypical shape in the form of a product equalizes the internal pressure of the mold and drags two surfaces, three surfaces or four surfaces or a middle part of the net-shaped structure three-dimensional. The filaments fused in random spiral shapes are formed into a flat plate-like shape having the apparent density described above. Front face, back face, left end face or right end face in the thickness direction of the three-dimensional net-like structure can be formed to a plane or an atypical concave/convex shape. The mold nozzle shape to form the three-dimensional net-like structure can be placed in a stick-like shape, any atypical shape (e.g. pipe shape or Y shape) or a combination thereof, as well as to provide various structures in three-dimensional network form. The three-dimensional net-like structure is formed into a highly dense sheet structure by the roller compression of the endless conveyors. The internal pressure of the mold is equalized to evenly eject the resin from the mold and form the respective layers. The three-surface or four-surface assembly of the extruded resin fused to manufacture a three-dimensional network as the sheet contacts drag conveyors to be formed into a specific shape. In other words, the three surfaces or the four surfaces of each layer in the molten resin assembly are formed into shapes corresponding to the shape of the final product. For example, the resin assembly can be dragged onto a polygonal conveyor as appropriate to form into the final product. One method of producing a three-dimensional web-like sheet uses a plurality of molds to extrude the molten resin downwards and free-fall the molten resin to the surface of the water or between the partially submerged carriers. This forms random spiral shapes to produce the three-dimensional lattice-like structure.
[00104] The three-dimensional net-shaped structure having the cross-section in the form similar to that of the mold opening is drained and transported by the rollers to a drying heat treatment tank to be subjected to drying heat treatment with the hot air by annealing. It is preferable to place different drag speeds of the rollers towards the flow and against the flow of the drying heat treatment tank. For example, the drag speed of rollers placed nearby to the outlet of the drying heat treatment tank is set to be lower than the drag speed of rollers placed nearby to the inlet of the drying heat treatment tank. drying. After the drying heat treatment, the three-dimensional net-like structure is cut to a desired length. The three-dimensional net-like structure may alternatively be cut to a previous desired length for drying heat treatment.
[00105] The three-dimensional net-shaped structure withdrawn from the water tank and drained is subjected to heat treatment by drying and annealing at a drying temperature for a predetermined duration of time. In the case of a low density polyethylene, the drying temperature is preferably not higher than the melting point of the low density polyethylene and is more preferably lower than the melting point by 10 to 70°C; In the case of a thermoplastic elastomer, the drying temperature is preferably not higher than the melting point of the thermoplastic elastomer and is more preferably lower than the melting point by 10 to 70°C.
[00106] The annealing process can put the three-dimensional net-shaped structure out of the water tank and drained into a frame in the compressed state, introduce heat treatment with hot air, and then release the three-dimensional net-shaped structure frame . In the case of a low density polyethylene, the drying temperature of such annealing is preferably not higher than the melting point of the low density polyethylene and is more preferably lower than the melting point by 10 to 70°C. In the case of a thermoplastic elastomer, the drying temperature is preferably not higher than the melting point of the thermoplastic elastomer and is more preferably lower than the melting point by 10 to 70°C.
[00107] As described above, annealing can be carried out in a post-process (hereinafter referred to as supplemental annealing) after forming the three-dimensional lattice-like structure shape in the water tank. Annealing can be carried out additionally during production (hereinafter referred to as during production annealing) by supplying heated water to the water tank.
[00108] Production during annealing is preferably carried out at a temperature that is lower than the melting point of the thermoplastic polyethylene resin or the melting point of the thermoplastic polyester elastomer by at least 10 to 70°C.
[00109] Production during annealing supplies of heated water in the range of 20 to 90°C (preferably in the range of 20 to 80°C or more preferably in the range of 25 to 50°C) for at least one pair of troughs, instead of supplying ordinary temperature water to the gutters, as well as heat-welding the filaments randomly and forming random loops while performing annealing. The temperature of the heated water is preferably 25 to 50°C for low density polyethylene and is 25 to 70°C for thermoplastic elastomer. Heated water can be provided, for example, by (A) heating fluid water to the gutters, (B) heating the entire water tank 18, (C) raising the temperature of gutters formed in a tank-like shape or a combination of that. The excessively high temperature of the heated water supplied to the gutters is likely to cause the resin to adhere to the gutters. This is thus desirable to control the heated water to a suitable temperature range, for example 10 to 60°C. Supplemental annealing wets the three-dimensional net-shaped structure taken from the water tank in heated water or causes the three-dimensional network pass through the hot air.
[00110] The annealing can be single annealing of the additional annealing also by the drying heating treatment or during annealing production with the water heated in the water tank or similar, it can be two-step annealing of the supplementary annealing later during annealing production, or it may be two-step annealing of the supplementary annealing performed twice. In the latter case, the temperature of the second supplemental annealing is set to be higher than the temperature of the first annealing.
[00111] The three-dimensional net-shaped structure of the invention manufactured by the above manufacturing method has the smoothness, high resilience and thermal expansion properties in both the longitudinal direction and the lateral direction. The thermal expansion properties differ in the longitudinal direction and in the lateral direction. According to the inventors' analysis, the mechanism for providing the elastic properties and the thermal expansion properties or more specifically the anxiotropic thermal expansion indices is complicated and not fully elucidated. It is, however, basically thought that variations in characteristics and fluctuations in the thickness of the filaments differ the forms of entanglement in the longitudinal direction and in the lateral direction in the process of free-fall, entanglement and cooling of the filaments by properly controlling the rate of decrease of the filament. raw material filament diameter in the proper range, melt viscosity, MFR, nozzle holes extrusion molding, filament loop formation, filament cooling, supplemental annealing by drying heat treatment, and during-production annealing .
[00112] The three-dimensional net-shaped structure has the properties of thermal expansion in the lateral direction and in the longitudinal direction according to the decrease rate of raw material filament diameter, nozzle hole diameter, drag speed of conveyors and annealing as the factors.
[00113] Chemicals can be added to the three-dimensional net-like structure of the invention to a certain extent that do not deteriorate performances at any stage of resin production to produce a molded product to provide various functions such as deodorization, antibacterial, elimination odor, mildew proof, coloring, fragrance, flame retardant, non-combustible, moisture absorbing or moisture removal functions.
[00114] Fig. 12 are diagrams illustrating modifications of apparatus 50 for manufacturing the core pad material in the case of four molding surfaces. Fig. 12A corresponds to Fig. 9B. A single or a plurality of projections 90a to 90c are provided on the surface of the pair of rollers 56 and 57 described above (the roller 57 and its projections are omitted from the illustration). These projections 90a to 90c are provided to form hollows on the side face of the three-dimensional lattice-like structure. Projections 90a to 90c are formed in an arc shape and a rectangular sectional shape. The concavities are theoretically formed into a rectangular shape, but the shedding of the resin filaments generates louvers to provide areas without the resin filaments. The concavities on the side face of the three-dimensional lattice-like structure are thus formed into a curved shape. Fig.12B corresponds to Fig.9C. A single or a plurality of projections 96 are provided on the surfaces of the pair of auger conveyors 54 and 55 described above (the auger conveyor 55 and its projections are omitted from the illustration). A can and a spring can be placed on the rotating bodies of the rollers 56 and 57 or the endless conveyors 54 and 55. The projections can be configured such that the can presses the projections from the outside synchronously with the rotation. This reduces the blinds and allows for more exact formation of the hollows. The other configuration is similar to Figs. 9B and 9C and is not specifically illustrated or described.
[00115] The following describes cushion core materials in accordance with the fifteenth to fifteenth representations. In terms of recycling, the polyolefin resin and polyester elastomer and/or polyurethane elastomer of the cushion core material should not be integrally molded. In the case where the polyolefin resin and the polyester elastomer and/or polyurethane elastomer have similar melting temperatures or similar cooling behaviors, however, these layers can be produced simultaneously with a view to improving productivity. There is also a need to change the density in each layer, a need for first forming an outer part including the polyester elastomer and/or polyurethane elastomer and subsequently forming a core part including the polyolefin resin, a need for changing the shape and a need for gain moldability. The renderings accordingly point to the thermoplastic resin's gentle recycling and ease of shape change.
[00116] As shown in Fig.13A, a core material for pad 101 according to a tenth representation is a three-dimensional lattice-like structure in a plate-like shape that is made of or primarily made of a thermoplastic resin as a material. raw material and is formed by spiral entanglement of a plurality of random filaments and partially bonded to the tangles by heat. Cushion core material 101 is composed of an inner area 101a including a polyolefin resin and an outer area 101b including a polyester elastomer or polyurethane elastomer. The boundary between the inner area 101a and the outer area 101b is shown by the solid line. The solid line is a ghost line showing the boundary. The same applies for the subsequent other representations. It is preferred that the density of two, three or four surface portions of the three-dimensional lattice-like structure is relatively higher than the density of another residual portion than the surface portions. More specifically, the core pad material 101 of the tenth embodiment (shown in Fig. 13A) is formed by two molding surfaces to have the highest density in areas of predetermined interior depth of the opposing surfaces and the lowest density of one. interior central area and has other surfaces left uneven. This configuration advantageously eliminates the need for further post-process processing. A pair of wide surfaces forming the lying surface and the mounting surface and a side face are easily molded by the endless conveyors or the like as described above to have flush edges compared to another side face.
[00117] A core material for pad 102 according to an eleventh representation (shown in Fig. 13B) is formed by three molding surfaces to have all surfaces except end faces and a side face aligned and have the highest density in interior areas predetermined depths of all surfaces except a right-hand face. The core pad material is comprised of an inner area 102a including a polyolefin resin and an outer area 102b including a polyester elastomer or polyurethane elastomer.
[00118] A core material for pad 103 according to a twelfth representation (shown in Fig. 13C) is formed by four molding surfaces to have all surfaces except end faces aligned and to have the highest density in depth areas. predetermined side and right side faces of the core material for pad 1 of the first representation and the lowest density in an inner core area. In other words, the areas of interior depths, predetermined, of all side faces are placed to have the highest density. Cushion core material 103 is comprised of an inner area 103a including a polyolefin resin and an outer area (103b) including a polyester elastomer or polyurethane elastomer.
[00119] A cushion core material 104 according to a thirteenth embodiment (shown in Fig. 13D) is configured to have a single or a plurality of (one in this embodiment) cavities 104c, for the purpose of further cost reduction. Cushion core material 104 is comprised of an inner area 104a including a polyolefin resin and an outer area 104b including a polyester elastomer or polyurethane elastomer.
[00120] A cushion core material 105 according to a fourteenth embodiment (shown in FIG. 14A) is configured to have three layer areas 105a, 105b, and 105c made of different raw materials (e.g., sequentially a layer including a polyester elastomer, a layer including a polyolefin resin and a layer including a polyurethane elastomer). Area 105a and area 105c may be made of an identical raw material (i.e., polyester or polyurethane elastomer), while area 105b may be made of a different raw material (i.e., polyolefin resin). The area of the three layers 105a, 105b and 105c are split along the longitudinal direction. A cushion core material 106 according to the fifteenth embodiment (shown in Fig. 14B ) is configured to have two layers of areas 106a and 106b made of different raw materials (one layer including a polyester or polyurethane elastomer and a layer including a polyolefin resin). The two layer areas 106a and 106b are separated along the width direction. As described above with reference to Fig.3, sheet 9A of the highest density (area filled with substantially no pores) and other area can be formed at predetermined locations along the width direction by the separate paths of different molding machines. extrusion. Although not specifically illustrated, this configuration is also applicable to various atypical shapes such as triangular shape and Y shape. As described above, manufacturing conditions such as raw material temperature and filament extrusion rate are readily adjustable by the application of raw materials separately to two or more areas supplied in the nozzle.
[00121] The following describes an apparatus 110 for manufacturing the pillow core materials accordingly in the tenth to fifteenth embodiments. As shown in Fig. 15, this manufacturing apparatus 110 includes an extrusion molding machine 111, a pair of endless conveyors 114 and 115 configured to have endless belts 112 and 113, a driving motor 16 configured to drive the belts. auger 112 and 13, a transmission 117 configured to have chains and gears and change the speeds of motion of the endless belts 112 and 113, a water tank 118 configured to pair the endless conveyors 114 and 115 partially submerged in water , a controller 119 and various gauges and indicators. The above description regarding apparatus 10 or apparatus 50 for manufacturing cushion core material is applied to endless belts 112 and 113 or the like.
[00122] As shown in Fig. 15, the extrusion molding machine 111 includes containers 131a and 131b which are configured to store identical or different thermoplastic resin raw materials, material feed ports 132a and 132b which are respectively provided above containers 131a and 131b, material supply pipes 133a and 133b which are respectively connected with containers 131a and 131b, a complex mold 135 (shown in Fig. 16) which is connected with material supply pipes 133a and 133b via filler elements 134a and 134b, and a nozzle 136 (shown in Fig. 16 ) which is detachably mountable to a lower end of the complex mold 135. The material supply pipe 133a is branched down the middle in a plurality of (four in the illustrated example) secondary pipes, which are placed above the material supply pipe 133b. The lower ends of the side pipes of the material supply pipe 133a are placed around the lower end of the material supply pipe 133b. As shown in Figs. 16A and 16B, the complex mold 135 is configured such that a frame-like dividing wall 139 is provided in an inner area of an outer frame 138 to divide the interior of the complex frame 135 into the two chambers 137a and 137b and thus prevent two different raw materials supplied through material supply pipes 133a and 133b to be mixed. Even in the case where an identical raw material is provided, it is preferable to provide the partition wall 139 for the purpose of separately adjusting extrusion rates. The above description regarding apparatus 10 or apparatus 50 for manufacturing the core material for pad is applied to the details of the internal mold configuration of the extrusion molding machine 111. The material supply tube 133a is branched into the four side pipes in the representation but can be branched into any suitable number of side pipes, for example two (shown in Fig. 17A) or three (shown in Fig. 17B).
[00123] Nozzle 136 has two or more areas configured to separately deliver raw materials. This configuration significantly facilitates adjustment of the extrusion index or the extrusion volume of the filaments and notably improves moldability. The above description regarding apparatus 10 or apparatus 50 for manufacturing the cushion core material is applied to the details of the mouthpiece. An available example is a nozzle 171 (shown in Fig. 18A) configured to have holes H arranged at substantially equal intervals or at suitable intervals (the size of the area filled with the holes of the H nozzle occupies 90% of the total area of the nozzle 171) . This nozzle 171 has an inner area 171a and an outer area 171b separated by a dividing wall 171c shown by the dotted line. The inner area 171a and the outer area 171b are respectively provided corresponding to the pipe supplying material 133a and the pipe supplying material 133b to separately and independently extrude filaments of an identical or different raw material. Another available example is a nozzle 172 (shown in Fig. 18B) configured such that an inner area 172a and an outer area 172b having a large number of holes H are separated by a dividing wall 172c shown by the dotted line and the area inner 172a is located on a side relative to outer area 172b. This configuration facilitates separation of the filaments corresponding to the inner area 172a. Another available example is a nozzle 173 (shown in Figs. 18C and 18D) configured such that an inner area 173a and outer areas 173b having a large number of holes H are separated by a dividing wall 173c shown by the dotted line and the inner area 173a is placed between outer areas 173b. Nozzle 173 includes areas 173d and 173e without holes H formed at predetermined locations for forming cavities and has rectangular guide members (e.g., pipes) 173f and 173g that extend below areas 173d and 173e.
[00124] Another available example is a nozzle 174 (shown in Fig. 19A) configured such that an upper area 174a, a central area 174b and a lower area 174c having a large number of holes H are separated by dividing walls. 174d and 174e shown by the dividing line to form a three-layer structure. Another available example is a nozzle 175 (shown in Fig. 19B) configured such that an upper area 175a and a lower area 175b having a large number of holes H are separated by a dividing wall 175c shown by the dotted line to form a two-layer structure. Another available example is a nozzle 176 (shown in Fig. 19C) configured such that a left area 176a and a right area 176b having a large number of holes H are separated by a dividing wall 176c shown by the dotted line to form a two-layer structure. Another available example is a nozzle 177 (shown in Fig. 19D) configured such that an area 177a having a large number of holes H and a slot (linear fit) 177b formed in a suitable location, for example in a parallel central part to a predetermined direction (longitudinal direction in the illustrated example) are separated by a dividing wall 177c shown by the dotted line. Slot 177b is located within the area of dividing wall 177c. The slot width, length and position of the slot (linear slot) 177b can be selected accordingly, In the case where the raw material is supplied from a mold identical to the area 177a having the large number of holes H and the slot ( slot linear) 177b, the waveform of Fig.3B is likely to be deformed and cause poor moldability. The configuration of the nozzle 177, however, allows raw materials to be separately and independently supplied from two or more different extrusion molding machines 111 to the holes H of the area 177a and the slot 177b. This advantageously forms a favorable waveform. Slot 177b can be replaced by holes H. In this case, it is preferable to increase the density of holes H. The mouthpiece can have any of several other configurations. The density of holes H formed in the mouthpiece is preferably 1 to 5 holes/cm 2 . The above description applies to the method of manufacturing such cushion core materials.
[00125] In the configurations of the pad core materials 101 to 106 of the fifteenth to fifteenth embodiments, resins that are difficult to separate or incapable of separation are divided into first area 101a and second area 101b and are separated from one to another for recycling. This allows for repeated recycling. A three-dimensional net-like structure can be fabricated to have boundary areas in accordance with the characteristics of thermoplastic resins. This ensures smooth recycling of thermoplastic resins. A further advantage is that later shape change is allowed by the simple operation of, for example, area separation. Separately and independently supplying the raw materials of a plurality of extrusion molding machines into the nozzle improves the moldability of the three-dimensional net-shaped structure.
[00126] In the cushion core material, the layer including the polyolefin resin and the layer including the polyester and/or polyurethane elastomer can be bonded together, can be sewn together or can be simply stacked without bonding or sewing. Stacking which is not limited to flat stacked layers but also includes providing an outer layer in an inner layer. The layer including the polyolefin resin and the layer including the polyester and/or polyurethane elastomer may be unified into an inner bag or the like having high air permeability or may be integrated with a cover or a case described later for quilting.
[00127] A mattress is provided for placing a cover over the entire side facing the layer including the polyester and/or polyurethane elastomer of the core cushion material. In the description of it here, the cover means a visible outer case. The permeable air cap has an air permeability in the thickness direction (JIS-L-1018) of preferably not lower than 10cc/cm2/sec, more preferably not lower than 50cc/cm2/sec or beyond preferably not lower than 100 cc/cm2/sec. The air permeable cover is, however, not limited to those having this property but may be a pouch made of a conventionally used fabric or material such as cotton or polyester or a quilting material by the thin double raschel fabric quilted of cotton or polyester. The permeable air cap can be configured by using different materials for the resting surface and the other surfaces. For example, the resting surface can be formed from a dual dimensional raschel mesh that has low skin irritation and high air permeability and allows the wearer to lie on. Surfaces other than resting surfaces may be covered with a quilt cover material. The peripheral edge of the three-dimensional mesh and the covering material can be sewn together. This takes advantage of excellent air permeability of the three-dimensional net-like structure placed inside. According to another possible configuration, an upper layer (A) is provided by covering a layer including a polyester and/or polyurethane elastomer in an inner bag of, for example, double raschel fabric, and a lower layer ( B) is formed of a PE lattice-like structure. The top layer and bottom layer (A) + (B) are entirely covered with a quilt cover or double raschel fabric cover.
[00128] A medical care adaptable mattress is provided to place a water impermeable cover over the entire side of the cushion core material facing the layer including the polyester and/or polyurethane elastomer. Waterproof cover is a cover made of, for example, artificial leather, polyvinyl chloride, waterproof polyurethane sheet, nylon taffeta or polyester taffeta. The waterproof cover can be configured by making the home cover and the other surfaces of different materials and sewing the edges of these surfaces.
[00129] An apparatus 210 for manufacturing a cushion core material in accordance with another embodiment is configured to provide a method of manufacturing a three-dimensional net-like structure that represses potential problems due to endless belt deformation, eliminates the need for finishing in the post-process, increases the degree of alignment, has applicability to atypical shapes and improves durability and a corresponding fabrication apparatus.
[00130] The above description of the first embodiment is applied to the apparatus 210 for manufacturing the pillow core material and the following describes a configuration which is different from the first embodiment. The apparatus 210 for manufacturing the cushion core material includes an extrusion molding machine 211, a pair of rolls 212 and 213 arranged horizontally across a predetermined gap, a pair of rolls 214 and 215 placed below and respectively aligned with the pair. of rollers 212 and 213 to be arranged horizontally across the predetermined gap (as shown in Fig. 20), an ignition motor configured to drive rollers 212 to 215, a transmission configured to have chains and gears and to change speeds of moving the rollers 212 to 215, a water tank configured to make the pair of rollers 212 and 213 partially submerged and the pair of rollers 214 and 215 completely submerged in water; a controller and several gauges and indicators. A modified configuration may omit one of the lower rollers shown in Fig.20 and use three rollers. A roll 224 formed in a circular sectional shape (shown in Fig. 22A) as well as rolls having various atypical sectional shapes are employable by the rolls 212 and 213. Available examples include a roll 225 formed to have a circumferential surface in a clamped sectional shape. (shown in Fig. 22B) a roller 226 formed to have a circumferential surface in a continuous convex-concave shape, for example a circumferential surface in a sectional mesh shape (shown in Fig. 22C), a roller 227 formed with one or more plus projection 227a (e.g. in a triangular shape or a circular shape) on a circumferential surface (shown in Fig.22D, a roll 228 formed in an elliptical sectional shape (shown in Fig.22E), a roll 229 formed in a triangular or beveled triangular sectional shape (shown in Fig. 22F) and a roll 230 formed into a polygonal sectional shape, eg octagonal sectional shape (shown in Fig. 22G). g.21, the rollers 212 to 215 respectively have steering axes 212a to 215a. Steering shafts 212a to 215a are supported by corresponding bearings to be rotatable and are driven by the ignition motor via the transmission in the directions of the arrows shown in Fig. 20. The apparatus 210 for manufacturing the pad core material described above eliminates the need for finishing such as cutting or shaping (profiling) in the post process to a net-like structure in a desired atypical shape, increases the degree of alignment, has applicability to atypical shapes and improves durability. Setting this representation immediately provides an unfinished product in the post-process to a desired shape and desired dimensions and thus eliminates the need for the post-process.
[00131] The apparatus can be configured to manufacture a three-dimensional net-like structure which is made of or primarily made of a thermoplastic resin as a raw material, formed by extrusion molding a plurality of filaments to be randomly tangled spirally and partially thermally bonded, cooled with a liquid and flame retardant material applied, covered with carbon fiber non-woven fabric or adding a flame retardant material to the thermoplastic resin.
[00132] As shown in Fig. 23, an apparatus 510 for manufacturing a cushion core material according to a fourth embodiment uses bent plate troughs 582 and 583, in place of endless belts or rollers, to form a shaped structure. mesh 501. Rails 582 and 583 extend perpendicular to the surface of the sheet and include surfaces having skid provided by, for example, polytetrafluoroethylene coating. Chutes 582 and 583 are formed into a rectangular shape in the side view. Rails 582 and 583 are arranged to have the gap gradually decreased from top to bottom. Rails 582 and 583 may have a fixed configuration or may have a movable configuration to vary the gap by the reciprocating driving devices 590 and 591 (e.g. hydraulic cylinders) as shown by the dotted line and thus change the density, shape and similar of the three-dimensional net-like structure from front to back and side to side. Another trough 584 is provided below troughs 582 and 583 to properly guide the three-dimensional net-like structure 501 into a downdraft of the towing machine.
[00133] The invention is described more specifically with reference to some examples. The invention is, however, not limited to these examples. The following methods were employed in the examples for measuring and evaluating characteristic values.
[00134] (1) Filament Diameter (mm) Resin strands were cut from a central portion of each sample. The resin filament thicknesses were measured 5 times with a caliper, and the average of 5 measured values was specified as the filament diameter with respect to S1 and S2. The filament diameter of an elastomer sample was estimated from the measurement result of a polyester sample. The temperature was set to 60°C with annealing and set to 23°C without annealing.
[00135] (2) Sample Thickness and Volume Density (g/cm3) Each sample was cut to size 30 cm x 30 cm. After being left under no load for 24 hours, the height of the same was measured in four different positions. The average of four measured values was specified as the sample thickness. The sample volume was calculated from the sample thickness, and the sample volume density was calculated by dividing the sample weight by the volume.
[00136] (3) Mean Diameter (mm) of Random Loops Each sample was cut to size 20 cm x 20 cm. With regard to random loops in irregular shapes formed in the extrusion direction, the lengths of the major axes of the ten loops were measured. The mean value was rounded down to the nearest centimeter and was specified as the mean diameter of the random loops.
[00137] (4) Hardness (N) Each sample was cut to size 30 cm (in length) x 30 cm (in width). The test piece was measured in accordance with JIS K 6400-2 2012 method A. The temperature test was 23°C, and the humidity was 50%.
[00138] (5) Impact of Elasticity (cm) Each sample was cut to size 30 cm (in length) x 30 cm (in width). The test piece was measured in accordance with JIS K 6400-3: 2011. A steel ball measuring 41.5 mm in diameter and 290 g in weight was used. The height drop was 500 mm. The test temperature was 23°C, and the humidity was 50%.
[00139] (6) Impact Elasticity Change Rate (%) after Repeated Load Test. Each sample was cut to size 30 cm (in length) x 30 cm (in width), and an impact elasticity (a) of the sample before a repeated load test was measured by the method described in (5). After measuring the impact elasticity, the sample was subjected to a repeated load compression test. The repeated load compression test was performed in accordance with method A of repeated compressive residual pressure test (fixed load method) of JIS K6400-4. Repeated load compression test was performed at temperatures of JIS K6400-4. Repeated load compression test was performed at temperatures of 23±2°C and relative humidity of 50±5%. Method A (fixed loading method) uses a pressure plate 25 cm in diameter and repeatedly compresses a sample under a load of 750 N ± 2-N 80000 times at a rate of 70 ± times per minute. A time duration when the maximum load 750 ± 20 N is applied is set to be no longer than 25% of a time duration required by repeated compression. After performing the test, the sample was left under no load for 100±0.5 minutes. An elastic impact (b) after repeated load testing was measured by the method described in (5). An index of impact elastic change (%) after repeated load testing was calculated according to the following equation by dividing the impact elasticity after repeated load testing by the impact elasticity before repeated loading test: (index of impact elasticity change (%) after repeated load test = (1-(b)/(a))x100.
[00140] (7) Compression deflection (%) Each sample was cut to size 30 cm (in length) x 30 cm (in width). The test pieces were measured in accordance with JIS K 6400-2: 2012 method E. The test temperature was 23°C, and the humidity was 50%
[00141] (8) Hysteresis loss (%) Each sample was cut to size 30 cm (in length) x 30 cm (in width). The test piece was measured in accordance with JIS K 6400-2:2012 method E.
[00142] (9) Thermal Expansion Index (%) before and after the Hot Air Drying Test. Each sample was cut to size 30 cm (in length) + 30 cm (in width). Markings were made in two positions 25 cm apart from each other in the longitudinal direction and two positions apart by 25 cm in the lateral direction of the test piece. The marking was made with a pen to be readily recognizable even after the dry heating process. After marking, the test piece was placed in a hot air drying oven for 30 minutes. The test piece was removed from the hot air drying oven and cooled at room temperature of 22°C for 30 minutes. After cooling, marking distances were measured at two different positions each in the longitudinal direction and the lateral direction. The mean values of the two respective positions were specified as the longitudinal length after testing. A measuring instrument capable of measuring down to 0.01 cm was used to measure all lengths. The thermal expansion index before and after the hot air drying test was calculated by (measured length-25)/25x100. The temperature of the hot air drying test was set to 90°C for the mixture of polyethylene resin and polyethylene thermoplastic elastomer.
[00143] Marking was made at two positions 25 cm apart in the longitudinal direction and two positions 25 cm apart in the lateral direction of the test piece before the dry heating process. The marking was made with a pen to be readily recognizable even after the dry heating process. After marking, the test piece was placed in a hot air drying oven and cooled at room temperature of 22°C for 30 minutes. After cooling, marking distances were measured at two different positions in each of the longitudinal direction and the lateral direction. The mean values of the two respective positions were specified as longitudinal length after testing and lateral length after testing. A measuring instrument capable of measuring down to 0.01 cm was used to measure all lengths. The thermal expansion index before and after the hot air drying test was calculated by (measured length-25)/25 x 100.
[00144] (9) Tensile Strength (N) Each sample was cut to size 20 cm (in length) x 5 cm (in width). The test piece was fixed to a jig with fixing brackets placed across a distance of 10 cm. The tension index was 10 cm/min. The room temperature during measurement was 20°C, and the humidity was 65%. A jig for fixing was used for the thermoplastic elastomer having a certain thickness. The test temperature was 23°C, and the humidity was 50%. Each sample was measured twice in each of the longitudinal direction and the lateral direction. The maximum point load was specified as the measurement value. Examples [Example 1]
[00145] Example 1 was an example of layer 43. The conditions employed were as follows: the screw diameter of an extrusion machine was 65 mm; the temperature of a mold was 205°C; the mold was 890 mm wide and 75 mm thick; hole spacing was 10 mm; nozzle hole diameter was 1.6 mm; and the air gap (distance between the lowest surface of the nozzle and the water level) was 67 mm. Hexane, benzene and ethylene as main raw materials were polymerized by a known method using a metallocene compound as a catalyst. A obtained ethylene α-olefin copolymer had a melt viscosity (Pa-s) of 1.05 at a flush index of 24.3 sec-1, 1.12 at a flush index of 60.8 sec-1, 1.15 at a flush index of 121.6 sec. -1, 1.18 at a flush index of 243.2 sec-1, 1.23 at a flush index of 608.0 sec-1 and 1.26 at a flush index of 1216 sec-1, the MFR of 12g/10 min and the density of 0.90 g/cm3. Ethylene/α-olefin copolymer filaments are ejected down a nozzle at an extrusion rate of 86 kg/h at a melt temperature of 180°C. The lower ends of the troughs were placed 36 mm below the nozzle surface and were submerged in water. A pair of stainless steel drag carriers 105 cm in width that were placed parallel to each other crossing an open width of 71 mm to be stowed partially above the surface of the water. The filaments ejected in the molten state were solidified in the troughs with water supply heated to 36°C. The filaments were brought into contact with one another and were entangled to form loops, while being fused at points of contact, as well as to form a structure. in the form of a three-dimensional network. The respective surfaces of the net-like structure in the molten state were placed between the drag carriers and were dragged into the 36°C heated water at the drag rate of 6.7 mm/sec to be solidified and flattened. The three-dimensional net-shaped structure was cut to a predetermined size and subjected to annealing by dry heating process with hot air at 60°C for 5 minutes. The resulting three-dimensional net-like structure was formed into a rectangular sectional shape of the filaments from 0.6 to 1.1 mm in diameter and had the flattened surfaces, the volume specific gravity of 53 kg/m3, the thickness of 75 mm, the width of 890 mm, the thermal expansion rates of 2.31% in the lateral direction and 1.52% in the longitudinal direction before and after the hot air drying test at 90°C for 5 minutes, the hysteresis loss of 28.7%, the elasticity impact of 31 cm and the impact index of the elasticity change of 0% after the repeated load test. The temperature was 19°C, and the humidity was 42%.
[00146] [Example 2] Example 2 was another example of layer 43. The conditions employed were as follows: the screw diameter of an extrusion machine was 40 mm: the temperature of a mold was 190°C; the mold was 500 mm wide and 25 mm thick; the spacing of the holes was 10 mm; nozzle hole diameter was 1.6 mm; and the air gap (distance between the lowest surface of the nozzle and the water level) was 38 mm. Filaments of an ethylene/α-olefin copolymer (produced from the same raw materials as those in Example 1) and polyethylene were ejected down a nozzle at an extrusion rate of 13 kg/h at a melt temperature of 160°C. lower ends of the troughs were placed 36 mm below the nozzle surface and were submerged in water. A pair of stainless steel 55 cm wide drag carriers were placed parallel to each other crossing an open width of 23 mm to be stowed partially above the surface of the water. The filaments ejected in the molten state were solidified in the troughs with water supply heated to 36°C. The filaments were brought into contact with each other and were entangled to form loops, while being fused at points of contact, as well as to form a structure. in the form of a three-dimensional network. The respective surfaces of the net-like structure in the molten state were placed between the drag carriers and were dragged in 36°C heated water at a drag rate of 4.1 mm/sec to be solidified and flattened. The three-dimensional net-shaped structure was cut to a predetermined size and subjected to annealing by the process of dry heating with hot air at 60°C for 5 minutes. The resulting three-dimensional net-like structure was formed into a rectangular sectional shape of filaments 0.6 to 1.1 mm in diameter and had flattened surfaces, gravity specific volume of 70 kg/m2, thickness of 25 mm , the width of 500 mm, the thermal expansion rates of 1.87% in the lateral direction and 1.39% in the longitudinal direction before and after the hot air drying test at 90°C for 5 minutes, the hysteresis loss of 28.6%, impact elasticity of 33 cm and impact elasticity change rate of 6.1% after repeated load test. The temperature was 21°C, and the humidity was 48%.
[00147] [Example 3] Example 3 was an example of layer 45. The conditions employed were as follows: the screw diameter of an extrusion machine was 65 mm; the temperature of one mold was 217°C; the mold was 900 mm wide and 30 mm thick; the spacing of the holes was 10 mm; the nozzle hole diameter was 1 mm; and the air gap (distance between the lowest surface of the nozzle and the water level) was 69 mm. A thermoplastic elastomer (Hytrel (trademark)) had a melt viscosity (Pa-s) of 1.26 at a close cut index of 60.8 sec-1, 1.28 at a close cut index of 121.6 sec-1, 1.30 at a close cut index of 243.2 sec-1. -1, 1.30 at the close cut index of 608.0 sec-1 and 1.33 at the close cut index of 1216 sec-1, the MFR of 14 g/10 min. and the density of 1.08 g/cm 3 . Thermoplastic elastomer filaments were ejected down a nozzle at an extrusion rate of 27.5 Kg./h at a melt temperature of 195°C. The lower ends of the troughs were placed 69 mm below the nozzle surface and were submerged in water. A pair of stainless steel 105 cm wide drag carriers were placed parallel to each other across the 70 mm open width to be stowed partially above the water surface. The filaments ejected in the molten state were solidified in the troughs with water supply heated to 63°C. The filaments were brought into contact with each other and were entangled to form loops, while being fused at points of contact, as well as to form the structure. in the form of a three-dimensional network. The respective surfaces of the net-like structure in the molten state were placed between the drag conveyors, were dragged at a drag rate of 3.9 mm/sec to be solidified and flattened, and annealed with hot water at 80°C. in the form of a three-dimensional net was cut to a predetermined size and subjected to annealing by dry heating process with hot air at 130°C for 5 minutes. The resultant of this three-dimensional net-like structure was formed into a rectangular sectional shape of the filaments 0.5 to 1.0 mm in diameter and had the flattened surfaces, the volume specific gravity of 71 kg/m3, the thickness of 30 mm, the width 900 mm, the thermal expansion rates of 0.78% in the lateral direction and 1.7% in the longitudinal direction before and after the hot air drying test at 130°C for 5 minutes, the hysteresis loss of 19.1%, the elasticity of impact of 33 cm and the impact elasticity change index of 0% after repeated load test. The temperature was 33°C, and the humidity was 48%.
[00148] [Example 4] Example 4 was another example of layer 45. The conditions employed were as follows: the screw diameter of an extrusion machine was 65 mm; the temperature of a mold was 225°C, the mold was 900 mm wide and 73 mm thick; the spacing of the holes was 10 mm; nozzle hole diameter was 1.6 mm; and the air gap (distance between the lowest surface of the nozzle and the water level was 69 mm. Filaments of a thermoplastic elastomer (Hytrel (trademark)) (the same raw material as that of Example 3) was ejected into under an extrusion rate nozzle of 40 kg/h at a melt temperature of 202°C. The lower ends of the troughs were placed 69 mm from the nozzle surface and were submerged in water. 105 cm wide drag was placed parallel to each other crossing a 72 mm wide opening to be stowed partially above the water surface. The filaments were brought into contact with one another and were entangled to form loops, while being fused at the points of contact, as well as to form a three-dimensional lattice-like structure. net-shaped structure in the molten state were placed between the drag carriers, were dragged at the drag rate of 2.7 mm/sec to be solidified and flattened, and annealed with hot water at 80°C. The net-shaped structure three-dimensional was cut to a predetermined size and subjected to annealing by dry heating process with hot air at 130°C for 5 minutes. The resulting three-dimensional net-like structure was formed into a rectangular sectional shape of filaments 0.5 to 1.2 mm in diameter and had flattened surfaces, volume specific gravity of 63 kg/m3, thickness of 73 mm, indices of thermal expansion of 1.22% in the lateral direction and 3.08% in the longitudinal direction before and after the hot air drying test, the hysteresis loss of 18.5%, the impact elasticity of 34 cm and the elasticity change index of the impact of 5.9% after repeated load test. The temperature was 30°C, and the humidity was 44%.
[00149] [Example 5] Example 5 was another example of layer 43. The conditions employed were as follows: the screw diameter of an extrusion machine was 40 mm; the temperature of a mold was 195°C; the mold was 500 mm wide and 51 mm thick; the spacing of the holes was 10 mm; the nozzle hole diameter was 1 mm; and the air gap (distance between the lowest surface of the nozzle and the water level) was 38 mm. Filaments of a blend including an ethylene/α-olefin copolymer (produced from the same raw materials as those in Example 1) as the main component and a non-combustible material was ejected down a nozzle at an extrusion rate of 23 kg/h in the melting temperature of 160°C. The lower ends of the troughs were placed 30 mm below the nozzle surface and were submerged in water. A pair of 55 cm wide stainless steel drag carriers were placed parallel to each other crossing a 40 mm opening width to be stowed partially above the water surface. The filaments ejected in the molten state were solidified in the troughs with a water supply heated to 36°C. The filaments were brought into contact with one another and were entangled to form loops, while being fused at points of contact, as well as to form a structure. in the form of a three-dimensional network. The respective surfaces of the net-like structure in the molten state were placed between the drag carriers and dragged in heated water of 36°C at a drag rate of 6.8 mm/sec to be solidified and flattened. The three-dimensional net-like structure was cut to a predetermined size and subjected to a dry heating process with hot air at 60°C for 5 minutes. This provided a three-dimensional lattice-like structure having a bulk density of 45 kg/m 3 . The resulting three-dimensional net-like structure was formed into a rectangular sectional shape of the filaments from 0.7 to 1.3 mm in diameter and had the flattened surfaces, the volume specific gravity of 50 kg/m3, the thickness of 51 mm, the width of 400 mm, the thermal expansion rates of 2.68% in the lateral direction and 1.28% in the longitudinal direction before and after the hot air drying test at 90°C for 5 minutes, the hysteresis loss of 27.0%, the impact of elasticity 24 cm and the impact elasticity change rate of 16.7% after repeated load testing. The temperature was 15°C, and the humidity was 52%.
[00150] [Example 6] Example 6 was another example of layer 43. The conditions employed were as follows: the screw diameter of an extrusion machine was 40 mm; the temperature of a mold was 195°C; the mold was 500 mm wide and 25 mm thick; hole spacing was 10 mm; the nozzle hole diameter was 1 mm; and the air gap (distance between the lowest surface of the nozzle and the water level) was 38 mm. Hexane, hexene and ethylene as main raw materials were polymerized by a known method, using a metallocene compound as the catalyst. Filaments of a blend including the resulting ethylene/α-olefin copolymer (produced from the same raw material as that of Example 1) as the main component and a non-combustible material were ejected down a nozzle at an extrusion rate of 17 kg/h at the melting temperature of 160°C. The lower ends of the troughs were placed 36 mm below the nozzle surface and were submerged in water. A pair of 55 cm wide stainless steel drag carriers were placed parallel to each other. crossing a 40mm opening width to be stowed partially above the water surface. The filaments ejected in the molten state were solidified in the troughs with a water supply heated to 36°C. The filaments were brought into contact with one another and were entangled to form loops, while being fused at points of contact, as well as to form a structure. in the form of a three-dimensional network. The respective surfaces of the net-like structure in the molten state were placed between the drag carriers and were dragged into the 36°C heated water at a drag rate of 4.5 mm/sec to be solidified and flattened. The three-dimensional net-shaped structure was cut to a predetermined size and subjected to a dry heating process with hot air at 60°C for 5 minutes. This provided a three-dimensional lattice-like structure having a bulk density of 65 kg/m3. The resulting three-dimensional net-like structure was formed into a rectangular sectional shape of the filaments from 0.7 mm to 1.3 mm in diameter and had the flattened surfaces, the volume specific gravity of 50 kg/m3, the thickness of 43 mm, the width 400 mm, the thermal expansion rates of 2.06% in the lateral direction and 1.22% in the longitudinal direction before and after the hot air drying test at 90°C for 5 minutes, the hysteresis loss of 30.0%, the impact of elasticity of 32 cm and the impact elasticity change index of 12.5% after repeated loading test. The temperature was 21°C, and the humidity was 48%.
[00151] [Example] Example 7 was another example of layer 43. The conditions employed were as follows: the screw diameter of an extrusion machine was 40 mm; the temperature of a mold was 205°C, the mold was 500 mm wide and 60 mm thick; the spacing of the holes was 10 mm; the nozzle hole diameter was 1 mm; and the air gap (distance between the lowest surface of the nozzle and the water level) was 38 mm. Hexane, hexene and ethylene as main raw materials were polymerized by a known method using a metallocene compound as the catalyst. Strands of a blend including the resulting ethylene/α-olefin copolymer (produced from the same raw materials as those in Example 1) and 20% by weight of an olefin block copolymer (polyolefin elastomer) were ejected down a nozzle in the extrusion rate of 22 kg/h at the melting temperature of 200°C. The lower ends of the troughs were placed 39 mm below the nozzle surface and were submerged in water. A pair of 55 cm wide stainless steel drag carriers were placed parallel to each other crossing a 40 mm wide opening to be stowed partially above the water surface. The filaments ejected in the molten state were solidified in the troughs with a water supply heated to 29°C. The filaments were brought into contact with one another and were entangled to form loops, while being fused at points of contact, as well as to form a three-dimensional lattice-like structure. The respective surfaces of the net-like structure in the molten state were placed between the drag carriers and dragged in heated water of 29°C at a drag rate of 4.5 mm/sec to be solidified and flattened. The three-dimensional net-like structure was cut to a predetermined size and subjected to a dry heating process with hot air at 60°C for 5 minutes. This provided a three-dimensional lattice-like structure having a bulk density of 65 kg/m3. The resulting three-dimensional net-like structure was formed into a rectangular sectional shape of the filaments from 0.8 to 1.5 mm in diameter and had the flattened surfaces, the volume specific gravity of 65 kg/m3, the thickness of 50 mm, the width of 405 mm, the thermal expansion rates of 2.72% in the lateral directions and 3.04% in the longitudinal direction before and after the hot air drying test at 90°C for 5 minutes, the hysteresis loss of 29.1%, the elasticity impact of 16 cm and the impact elasticity change rate of 5.5% after repeated loading test. The temperature was 12°C, and the humidity was 45%.
[00152] [Comparative Example 1] A net-like structure of a thermoplastic polyester elastomer manufactured by Toyobo Co., Ltd. (BREATHAIR (trademark)) (thickness 45 mm and width 400 mm) was examined by the respective tests above. The net-shaped structure had the specific volume gravity of 40 kg/m3, the thermal expansion rates of -0.12% (contracted) in the lateral direction and -0.32% (contracted) in the longitudinal direction before and after the drying test. of hot air at 130°C for 5 minutes, the hysteresis loss of 70.4%, the impact elasticity of 22 cm and the impact elasticity change rate of 68.2% after repeated load test.
[00153] [Comparative Example 2] A net-like structure of a thermoplastic polyester elastomer manufactured by Toyobo Co., Ltd. (BREATHAIR (trademark)) (thickness 25 mm and width 400 mm) was examined by the respective tests above. The net-shaped structure had a volume specific gravity of 50 kg/m3, thermal expansion rates of -0.20% (contracted) in the lateral direction and -0.28% (contracted) in the longitudinal direction before and after. of the hot air drying test at 130°C for 5 minutes, the hysteresis loss of 81.0%, the impact elasticity of 21 cm and the impact elasticity change rate of 4.8% after the repeated load test.
[00154] A pad core material 601 according to the sixteenth embodiment is used to produce a pad 620. As shown in Figs. 24 and 25, a lightweight urethane foam 607 is stacked on a single face of a layer 605 three-dimensional net-like structure in a plate-like shape that is made of or primarily made of a thermoplastic resin as a raw material and is formed by entanglement spiraling a plurality of filaments randomly and partially binding the tangles by heat.
[00155] The thermoplastic resin used to produce the layer 605 three-dimensional net-like structure is one or two or more selected from the group consisting of polyester elastomers and polyurethane elastomers. The above description regarding layer 43 and the above description regarding layer 45 are respectively applied to the polyester resin and to the polyester elastomer. The following describes the polyurethane elastomer.
[00156] The polyurethane elastomer can be any elastic polymer having urethane bond in the backbone. The polyurethane elastomer can be, for example, a block copolymer including a hard segment comprised of a disocyanate and a glycol and a light segment comprised of a polyester, a polyether; polycarbonate or an aliphatic polyol with a disocyanate as appropriate. One or a mixture of two or more polyurethane elastomers can be used. An antimicrobial, non-combustible material or flame retardant can be mixed with the polyurethane elastomer as the raw material to provide a layer including the polyurethane elastomer with the corresponding function.
[00157] Lightweight urethane foam layer 697 has an open cell foam and/or continuous space. The lightweight urethane foam may be a commonly called low elastic urethane foam having impact elasticity of lower than 25%, not higher than 20% or not higher than 15% or a filter foam having elasticity. impact of not lower than 25% or not lower than 30% and not higher than 40%, not higher than 60% or not higher than 85%. Impact elasticity is measured in accordance with JIS K6400. Lightweight urethane foam can be a commercially available product such as Tempur (trademark) (manufactured by Tempur World Inc.), EGR series low elasticity foam (manufactured by INOAC CORPORATION, Moltofilter MF series (manufactured by INOAC CORPORATION), Moltofilter CF series (manufactured by INOAC CORPORATION) and Everlight series (manufactured by Bridgestone Corporation) An antimicrobial, non-combustible material or flame retardant can be mixed into the lightweight urethane foam or can be applied to the surface of the lightweight urethane foam to provide the corresponding functions. It is preferable to use filter foam having the impact elasticity of not lower than 25% and not higher than 85% for urethane foam, in terms of utilizing the repulsive force than the net-like structure three-dimensional in the lowest layer intrinsically has and thus provides the resting surface with adequate repulsive strength, in addition to lightness.
[00158] Lightweight urethane foam layer 607 is roughly classified as polyether urethane foam and polyester urethane foam. Also these urethane foams can be used, but polyether urethane foam is preferable in terms of hydrolysis and water absorption improbability.
[00159] Lightweight urethane foam layer 607 generally has an open cell foam size not lower than 5 cells/25 mm and not higher than 10 cells/25 mm measured in accordance with JI K6400-1, Appendix 1. This extension satisfies both the heating effect evenly to the entire resting surface and the effect of providing light and comfortable sleep. The most preferable upper limit is 30 cells/25mm, and furthermore preferable upper limit is 25 cells/25mm.
[00160] The lightweight urethane foam layer 607 preferably has a thickness of 3mm to 50mm. The thickness ratio of the lightweight urethane foam layer 607 is generally set to 1/3 to 1/9 of the thickness of the three-dimensional net-like structure, but is not limited to this range. The 607 lightweight urethane foam layer is endless in the length direction and is cut to a suitable size (eg 1800 to 2300 mm), although this is not restrictive.
[00161] In the cushion core material 601 of this aspect, the layer three-dimensional net-like structure and the lightweight urethane foam can be bonded together, sewn together, or simply stacked without binding or sewing. The layered three-dimensional net-like structure and lightweight urethane foam can be unified into an inner bag 609 or the like having high air permeability to be provided as a cushion 620 or can be integrated with a padding case.
[00162] A cushion core material 701 according to the seventeenth embodiment (shown in Fig. 26) has a plurality of continuous grooves 701a that are formed from the lowest surface toward the upper surface of a three-dimensional net-like structure. layers to pass through the short lateral direction and are arranged at predetermined intervals along the longitudinal direction. The continuous grooves 701a are spread out when the three-dimensional net-like structure is folded up. A lightweight urethane foam stacked on the three-dimensional net-like structure is placed to be such a thickness as to allow the lightweight urethane foam to be folded upwards accompanied by the upward-folding of the three-dimensional net-like structure. This configuration provides a non-splitting, non-splitting, seamless pad and eliminates problems such as misalignment of pad layers and unevenness of pad layers. This cushion core material 701 is applicable to a reclining bed core material.
[00163] A cushion core material 801 according to an eighteenth embodiment (shown in Fig. 27) is configured such that continuous grooves 801a are formed on all four side faces of a three-dimensional lattice-like structure as shown. in Fig. 27A. More specifically, continuous inserts 801a are formed in interlacing on the lower surface of the core cushion material 801 to include a plurality of inserts that are formed to 'pass through the short lateral direction and are arranged at predetermined intervals or suitable intervals in the direction. longitudinal and a plurality of slots which are formed from the lower surface towards the upper surface of the three-dimensional net-like structure to pass through the longitudinal direction and are arranged at predetermined intervals or suitable intervals in the short lateral direction (shown in Fig. .27C). Fig. 27B illustrates a state that one side face outside the four side faces of the core pad material 801 is curved upwards.
[00164] In accordance with this embodiment, the continuous inserts 801a are formed in interlacing on the lower surface of the core cushion material 801. This configuration enables the core cushion material 801 to be curved upward from any of the four side faces. For example, in an application where a floor pad or the like is placed on the back side of the mattress, the mattress can be curved in such a way that the head back of a person lying on the mattress is lifted or the mattress can be curved in such a way. so that the side of the body of a person lying on the mattress is lifted. An application of the cushion core material to a conventional stationary bed achieves the similar effects of a reclining bed, for example lifting a leg portion or a backrest portion, as well as lifting the right half or left half of the body from the lying position.
[00165] Additionally, in accordance with this embodiment, forming continuous grooves in the lower surface of the core cushion material 801 divides the lower surface of the core cushion material 801 into a plurality of areas. In accordance with this representation, as shown in Fig. 27C, the lower surface of the central pad material 801 is divided into sixteen to form sixteen blocks 801c. Placing a floor pad 806 or the like on block 801c enables only part of the core pad material 801 to be lifted as shown in Fig. 28A. Additionally, a plurality of different places on the cushion core material 801 can be lifted as shown in Fig.28B or Fig.28C. This configuration provides the core material for cushion 801 in which an elderly person, an invalid or a wounded person or a sick person as well as a healthy person rests in a comfortable position. This is helpful in preventing congestion, chafing, pressure sores and the like.
[00166] A mattress of the invention is provided by placing an air permeable cover under the entire side face facing the lightweight polyurethane foam of the core cushion material. In the description of this, the cover means a visible outer case. The permeable air cap has the air permeability in the thickness direction (JIS-L-1096) is preferably not lower than 10 cc/cm2/sec., more preferably not lower than 50 cc/cm2/sec. or moreover preferably not lower than 100 cc/cm2/sec. The air-permeable cover is, however, not limited to those having this property but may be a pouch made from a conventionally used fabric or material such as cotton or polyester or a quilting material made from a thin double raschel fabric quilted with cotton or polyester. The permeable air cap can be configured by using different material for the resting surface and the other surfaces. For example, the resting surface can be formed of a three-dimensional double raschel knit that has low skin irritation and high air permeability and allows the wearer to lie down directly. Surfaces other than the resting surface may be coated with a cover sheet material. The peripheral edge of the three-dimensional mesh and the covering material can be sewn together. This takes advantage of the excellent air permeability of the core material for cushion placed inside.
[00167] A medical care adaptable mattress is provided by placing a waterproof cover over the entire side of the core cushion material facing the lightweight polyurethane foam. The waterproof cover is a cover made of, for example, artificial leather, polyvinyl chloride, water repellent polyurethane sheet, nylon taffeta or polyester taffeta. The waterproof cover can be configured by making the resting surface and other surfaces of different materials and stretching the edges of these surfaces.
[00168] The description above considering the fabrication method of the core material for the cushion is applied to this representation.
[00169] In the process of cutting the three-dimensional lattice-shaped structure fabricated as described above by melting means such as a hot plate, hot wire, ultrasonic knife, ultrasonic cutter or the like, the cutting surface may be flattened or a continuous fit can be formed. As shown in Fig. 29, the continuous fit can be formed by a procedure using a hot plate 909d formed by coupling thin plates 909c perpendicularly with an iron plate 909b. This procedure presses the thin plates 909c into a surface layer 945a at right angles and strips the hot plate 909d after forced cooling or natural cooling. Forming the continuous fit with heat or ultrasonic wave I melted the cut surface to increase strength and close the margin gap. This advantageously prevents invasion of water and microorganisms even in an application using hollow filaments.
[00170] The invention is not limited to the above representations but various modifications, changes and additions may be made to the representations without departing from the scope of the invention. Such modifications as well as equivalents thereof are also included in the scope of the invention.
[00171] Reference Material List 1 central material for cushion; 41 three-dimensional net-like structure; 43.45 layer; 2 cushion core material; 3 cushion core material; 4 cushion core material; 4A, 4B cavity; 5 cushion core material; 5A, 5B cavity; 5C, 5D recycled member; 6 cushion core material; 6A, 6B, 6C high density area; 7 cushion core material; 8 cushion core material; 8A high density area; 9 cushion core material; 9A sheet; 75th slot (linear through snap); 10, 50, 110, 210, 510 apparatus for making cushion core material; 11 extrusion molding machine; 12, 13 endless belt; 12a, 13a endless chain; 14, 15 endless conveyor; 16 ignition engine; 17 transmission; 18 water tank; 19 controller; 20 board member; 22 release; 23 belt; 24 convex shape; 25 concave shape; 26 toothed shape; 27 convex-concave shape; 14a, 14c, 15a, 15c sprocket drive shaft; 14, 14d, 15b, 15d driven axis; 21 assembly of the filament; H water level; 36 gutter; 37a, 37b inclined plane; 31 container; 32 material feed port; 33 mold; 34 mouthpiece; 20 filament; 38 water supply port; 21 filament assembly; 39 water supply port; 38 supply pipe; 50 manufacturing apparatus; 54a, 55a rotary axis; 54.55 endless conveyor; 56a 57a rotary axis; 56, 57 roll; 54b, 54c bevel gear; 56b, 57b bevel gear; M engine; 58a, 58b bearing; 59a 59b endless conveyor; 66, 67 roll; 64a 65a rotary axis; 64, 65 endless conveyor; 66a, 67a rotary axis; 66, 67 roll; 68a, 68b bearing; 69a, 69b trough; 71 mouthpiece; 72 mouthpiece; 74a to 74c slot (linear through hole); 74 mouthpiece; 75th slit (linear through hole); 75 mouthpiece; 76th slit (linear through hole); 76 mouthpiece; H hole; 77c,77d area; 77a,77b guide member (e.g. barrel); 77 mouthpiece; 96 projection; 101 cushion core material; 101st indoor area; 101b outdoor area; 102 cushion core material; 102a indoor area, 102b outdoor area; 103 cushion core material; 103a indoor area, 103b outdoor area; 104 cushion core material; 104c cavity; 104th indoor area; 104b outdoor area; 105 cushion core material; 105a, 105b, 105c area; 106 cushion core material; 106a, 106b area; 701 cushion core material; 701a continuous fit; 801 cushion core material; 801a continuous fit; 801c block; 806 floor pad; 909b iron plate; 909c thin plate; 909d hot plate; 945th surface layer.

权利要求:
Claims (13)
[0001]
1. Cushion core material (1) comprising a three-dimensional net-like structure in a plate shape which is formed by spirally entangling a plurality of filaments, which are made of or primarily made of a thermoplastic resin as a raw material , randomly and partially bonded to heat entanglements, wherein the three-dimensional net-like structure has a first layer (43) that includes a thermoplastic resin and a second layer (45) that is stacked on a single surface or both surfaces of the first layer (43) and includes a thermoplastic resin different from the thermoplastic resin of the first layer (43); wherein the second layer thermoplastic resin (45) has a higher melting temperature than the first layer thermoplastic resin (43); both the first layer (43) and the second layer (45) are three-dimensional net-like structures, and the first (43) or the second layer (45) has a longitudinal direction corresponding to an extrusion direction, a lateral direction and a thickness direction perpendicular to the extrusion direction and is comprised of a thermoplastic polyethylene resin, a thermoplastic polyester elastomer or a mixture of a thermoplastic polyethylene resin and a thermoplastic polyethylene elastomer; characterized in that the first layer (43) or the second layer (45) has an impact resilience, which is measured in accordance with JIS K 6400-3: 2011, of not lower than 13 cm, a loss of hysteresis, which is measured in accordance with JIS K 6400-2: 2012 method E, not higher than 34% and not lower than 13%, and a thermal expansion index of 0 to 8% in the longitudinal direction, which is calculated by (measured length-25)/25x100, where the measured length was obtained by measuring the marking distance after a hot air drying test, where the marking was made at a distance of 25cm from each other in the direction longitudinal before hot air drying test, hot air drying test which is carried out at a temperature of 90°C for 30 minutes with regard to polyethylene thermoplastic resin which is carried out at a temperature of 130°C for 30 minutes with regard to thermoplastic elastomer polyester and which is carried out at a temperature of 90° C for 30 minutes with regard to the mixture of the thermoplastic polyethylene resin and the thermoplastic polyethylene elastomer.
[0002]
2. Cushion core material (1) according to claim 1, characterized in that the first layer (43) includes a polyolefin resin, and the second layer (45) includes a polyester elastomer and/or polyurethane elastomer.
[0003]
3. Cushion core material (1) according to claim 1 or 2, characterized in that the core material is comprised of the structure in the form of a three-dimensional network.
[0004]
4. Cushion core material (1) according to claim 2 or 3, characterized in that the layer includes polyolefin resin which has a thickness of not less than 8 mm and less than 250 mm, and wherein the layer including the polyester elastomer and/or polyurethane elastomer has a thickness of 3 mm to 160 mm.
[0005]
5. Cushion core material (1) according to claim 1, characterized in that the first layer (43) or the second layer (45) has a thermal expansion index of 0 to 8% in the lateral direction, which is calculated by (measured length-25)/25x100, where the measured length was obtained by measuring the marking distance after a hot air drying test, where the marking was made at a distance of 25cm from each other in the direction side before hot air drying test, hot air drying test which is performed at temperature of 90°C for 30 minutes with regard to polyethylene thermoplastic resin, which is performed at temperature of 130°C for 30 minutes with regard to the thermoplastic polyester elastomer and which is carried out at a temperature of 90° C for 30 minutes with regard to the mixture of the thermoplastic polyethylene resin and the thermoplastic polyethylene elastomer.
[0006]
6. Cushion core material (1) according to claim 1, characterized in that the first layer (43) or the second layer (45) has an anxiotropic thermal expansion characteristic providing different thermal expansion rates in the longitudinal direction and in the lateral direction.
[0007]
7. Cushion core material (1) according to claim 1, characterized in that the first layer (43) or the second layer (45) has an impact elasticity change index of not higher than 20 % after a repeated load test.
[0008]
8. Cushion core material (1) according to claim 1, characterized in that the first layer (43) or the second layer (45) has an apparent density of 0.025 g/cm3 to 0.2 g/cm3 , a thickness of 5 mm to 500 mm in each layer and a filament diameter of 0.1 mm to 1.5 mm.
[0009]
9. Cushion core material (1) according to claim 1, characterized in that the thermoplastic polyethylene resin is selected from the group consisting of polyethylene, an ethylene/α-olefin copolymer resin which is primarily made of ethylene and an α-olefin containing 3 or more carbon atoms and a vinyl acetate/ethylene copolymer resin.
[0010]
10. Cushion core material (1) according to claim 1, characterized in that the blend of the thermoplastic polyethylene resin and the thermoplastic polyethylene elastomer is a blend of an α-olefin/ethylene copolymer resin, which is mainly made of ethylene and an α-olefin containing 3 or more carbon atoms, and the thermoplastic elastomer of polyethylene, and a content of thermoplastic polyethylene elastomer in the blend that is not higher than 45% by weight.
[0011]
Cushion core material (1) according to claim 1, characterized in that it has a plurality of surfaces, between which two surfaces, three surfaces or four surfaces are molded and has multiple layers having different bulk densities.
[0012]
Cushion comprising the core cushion material (1) as defined in any one of claims 1 to 4, characterized in that at least a partial area on one side of the core cushion material facing the second layer is covered with a permeable air cover.
[0013]
13. Medical cushion, comprising the core cushion material (1) as defined in any one of claims 1 to 4, characterized in that at least a partial area on one side of the core cushion material faces the second layer be covered with a waterproof material.

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法律状态:
2020-04-28| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-11-03| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2022-01-04| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 23/02/2015, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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JP2015/000885|2014-02-23|

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JP2014032381|2014-02-23|

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JP2014052852|2014-03-15|

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PCT/JP2015/000885|WO2015125497A1|2014-02-23|2015-02-23|Core material for cushion, and cushion|

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